A multi-layered construction of dissimilar synthetic polymeric materials comprising a first layer of synthetic polymeric material containing a vinyl resin, at least one plasticizer for said vinyl resin and from about 0.5 to about 20% by weight a chemical compound containing reactive hydrogen selected from the group consisting of hydroxy, carboxy, amido, amino, imino and mercapto;
- and a second layer of synthetic polymeric material containing a member of the group consisting of polyurethane and acrylated polyurethane compositions, containing from about 0.5% to about 10% by weight of a free available isocyanate, said two layers of synthetic polymeric materials being bonded in a strong and permanent primary chemical bond therebetween by a reaction product of said chemical compound containing reactive hydrogen and said polyurethane or acrylated polyurethane composition.