Process for the preparation of supported metal catalysts
AssigneeMagyar Tudomanyos Akademia Kosponti Hivatala
InventorsTibor Mathe, Antal Tungler, Jozsef Petro
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AssigneeMagyar Tudomanyos Akademia Kosponti Hivatala
InventorsTibor Mathe, Antal Tungler, Jozsef Petro
Estimating the term…
The invention relates to a new process for the preparation of a supported metal catalyst containing at least one metal belonging to Group A and optionally at least one metal belonging to Group B, wherein Group A encompasses the metals palladium, rhodium, ruthenium, platinum, iridium, osmium, silver, gold and cadmium and Group B encompasses the metals zinc, mercury, germanium, tin, antimony and lead. According to the invention, the metal(s) is (are) applied onto the support in the presence of at least one compound of the general formula (I), ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each stands for a straight-chained or branched C.sub.1-20 alkyl group, a C.sub.1-4 hydroxyalkyl group or a phenyl-(C.sub.1-4 alkyl) group optionally having additional substituents, preferably C.sub.1-4 alkyl groups, on the phenyl ring, and X is hydroxy group or the residue of an organic or mineral acid. According to the invention, highly active catalysts can be prepared by an easy and economical process.
A process for the preparation of a supported metal catalyst containing at least one metal belonging to Group A and optionally at least one metal belonging to Group B, wherein Group A metals are selected from the group consisting of palladium, rhodium, ruthenium, platinum, iridium, osmium, silver, gold and cadmium and Group B metals are selected from the group consisting of zinc, mercury, germanium, tin, antimony and lead, by reductive deposition of the metal(s) onto the support with a solution containing the ions or compounds of the metal(s) in question and then reducing the support, characterized in that the metal(s) is (are) applied onto the support in the presence of at least one compound of the general formula (I), ##STR3## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each stands for a straight-chained or branched C.sub.1-20 alkyl group, a C.sub.1-4 hydroxyalkyl group or a phenyl-(C.sub.1-4 alkyl) group optionally having additional substituents, preferably C.sub.1-4 alkyl groups, on the phenyl ring, and
A process for the preparation of a supported metal catalyst containing at least one metal belonging to Group A and optionally at least one metal belonging to Group B, wherein Group A metals are selected from the group consisting of palladium, rhodium, ruthenium, platinum, iridium, osmium, silver, gold and cadmium and Group B metals are selected from the group consisting of zinc, mercury, germanium, tin, antimony and lead, by reductive deposition of the metal(s) onto the support by impregnating the support with a solution containing the ions or compounds of the metal(s) in question to form a suspension and then reducing the suspension, characterized in that the metal(s) is (are) applied onto the support in the presence of at least one compound of the general formula (I), ##STR4## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each stands for a straight-chained or branched C.sub.1-20 alkyl group, a C.sub.1-4 hydroxyalkyl group or a phenyl-(C.sub.1-4 alkyl) group optionally having additional substituents, preferably C.sub.1-4 alkyl groups, on the phenyl ring, and
A process for the preparation of a supported metal catalyst containing at least one metal belonging to Group A and optionally at least one metal belonging to Group B, wherein Group A metals are selected from the group consisting of palladium, rhodium, ruthenium, platinum, iridium, osmium, silver, gold and cadmium and Group B metals are selected from the group consisting of zinc, mercury, germanium, tin, antimony and lead, by reductive deposition of the metal(s) onto the support by impregnating the support with a solution containing the ions or compounds of the metal(s) in question to form a suspension and then reducing the suspension, characterized in that the metal(s) is (are) applied onto the support in the presence of at least one compound of the general formula (I), ##STR5## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each stands for a straight-chained or branched C.sub.1-20 alkyl group, A C.sub.1-4 hydroxyalkyl group or a phenyl-(C.sub.1-4 alkyl) group optionally having additional substituents, preferably C.sub.1-4 alkyl groups, on the phenyl ring, and
Dependencies are inferred from the claim text.