Back to results
US 4,360,617 AGranted
Stabilizer systems of triarylphosphites and phenols
AssigneeCiba-Geigy Corporation
InventorsHelmut Muller, Kurt Schwarzenbach
Life of this patent
Estimating the term…
Abstract
Use of symmetrical triarylphosphites of the general formula I ##STR1## wherein R.sub.1 is tert.-butyl, 1,1-dimethylpropyl, cyclohexyl or phenyl, and one of R.sub.2 and R.sub.3 is hydrogen and the other is hydrogen, methyl, tert.-butyl, 1,1-dimethylpropyl, cyclohexyl or phenyl, in combination with phenolic antioxidants for stabilizing organic polymers which contain hetero atoms, double bonds or aromatic rings.
Claims10
A stabilized composition consisting essentially of
- (a) a polymer which is polybutadiene, polyisoprene, polystyrene, a styrene copolymer, a styrene graft polymer, a halogen-containing vinyl polymer or copolymer, a polymer derived from an alpha,.beta.-unsaturated acid, a polyacrylate, a polymethacrylate, a polyacrylic amide, polyacrylonitrile, a polymer derived from an unsaturated alcohol or its acyl or acetyl derivatives, a polyacetal, a polyurethane, a polycarbonate, a polyamide or a polyester, and
- (b) from 0.005 to 5% by weight of component (a) of a mixture of
- (1) a triaryl phosphite of the formula ##STR4## wherein R.sub.1 represents tert-butyl or 1,1-dimethylpropyl,
- R.sub.2 represents methyl, tert-butyl or 1,1-dimethylpropyl, and
- (2) a hindered phenolic antioxidant selected from the group consisting of 2,6-di-tert-butyl-4-methylphenol, 1,3,5-tris(3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate, n-octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, 1,3,5-tris-(3,5-di-tert-butyl-4-hydroxybenzyl)-2,4,6-trimethylbenzene, hexamethylene bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate), pentaerythrityl tetrakis(3,5-di-tert-butyl-4-hydroxyhydrocinnamate), 2,2'-methylene-bis(4-methyl-6-tert-butylphenol) and N,N'-hexamethylene-bis(3,5-di-tert-butyl-4-hydroxyhydrocinnamamide), with the ratio of the phosphite to antioxidant being 10:1 to 1:5.
2 more elements
Dependencies are inferred from the claim text.