Methyl glucoside-amine-based polyether polyols and process of preparation
AssigneeOlin Corporation
InventorsStephen Fuzesi, John G. Bayusik
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Abstract
A novel process for the preparation of methyl glucoside-amine-based polyols which involves reacting starch with methanol in the presence of an acid catalyst to form a crude methyl glucoside reaction product. An amine compound is admixed with the reaction product, and the mixture is then oxyalkylated with a lower alkylene oxide. Polyurethane foams may be prepared by reacting the resulting polyether polyols with an organic polyisocyanate in the presence of a foaming agent and a reaction catalyst. The physical properties of the resulting foams are excellent.
Claims21
A process for preparing a polyether polyol which comprises:
- a. forming a crude methyl glucoside reaction product by reacting in the presence of a catalytic proportion of an acid catalyst,
- (1) starch and
- (2) methanol,
- said reaction being carried out at an elevated pressure and by reacting at least a stoichiometric proportion of said methanol with said starch, and
- b. admixing said crude methyl glucoside reaction product with an amine in the presence of a basic catalyst, maintaining said mixture at a temperature of from 100.degree. to 165.degree. C., and introducing into said mixture an alkylene oxide having between 2 and about 6 carbon atoms, said amine being employed in an amount of at least about 0.1 mole to about 10 moles per glucose unit weight of starch and being selected from the group consisting of an aliphatic amine having 1-8 carbon atoms, an aromatic primary amine having 6-8 carbon atoms, an alkanolamine in which each alkanol group contains 2-5 carbon atoms, and a mixture thereof.
Dependencies are inferred from the claim text.