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US 4,359,419 AGranted
Bleed-fast cationic dye stuffs
AssigneeScott Paper Company
InventorAlex Pociluyko
Life of this patent
Estimating the term…
Abstract
Bleed-fast, dyed cellulosics particularly absorbent papers have been obtained with a particular class of water-soluble, cationic dyes reacted with a water-soluble dialdehyde, preferably glyoxal or glutaraldehyde. An aqueous printing fluid containing the water-soluble cationic dye and the dialdehyde, upon drying, produces a water-resistant dyestuff having improved bleed fastness upon cellulosic fibers.
Claims5
The reaction product of a dialdehyde selected from the group consisting of glyoxal and glutaraldehyde and a cationic, water-soluble dyestuff of the formulae:
- ##STR4## wherein R.sup.0 is hydrogen, lower-alkyl or hydroxy-lower-alkyl;
- R.sup.1 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl;
- R.sup.2 is lower-alkyl, lower-alkenyl, hydroxy-lower-alkyl or (lower-alkylene)-NR.sup.0 Y or R.sup.1 and R.sup.2 together with the nitrogen atom, are pyrrolidino, piperidino or 4-lower-alkanoyl piperazino;
- Y is hydrogen or ##STR5## wherein R is hydrogen, lower-alkyl, lower-alkenyl, phenyl or phenyl-lower-alkyl;
- A is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge;
- k is a small integer whose value is dependent on the nature of A such that it has a range from one to two;
- R.sup.8 is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl;
- R.sup.9 is lower-alkyl, hydroxy-lower-alkyl or NH.sub.2 ;
- R.sup.10 is lower-alkyl or lower-alkenyl;
- A.sup.1 is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge;
- g is a small integer whose value is dependent on the nature of A.sup.1 such that it has a range from one to two;
- R.sup.8' is lower alkyl;
- R.sup.9' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl;
- R.sup.10' is lower-alkyl, lower-alkenyl or hydroxy-lower-alkyl or
- R.sup.9' and R.sup.10' together with the nitrogen atom are morpholino;
- A.sup.2 is a dyestuff residue attached to the quaternary ammonium nitrogen atom through a lower-alkylene bridge;
- h is a small integer whose value is dependent on the nature of A.sup.2 such that it has a range from one to two;
- and
- An is an anion.
16 more elements
Dependencies are inferred from the claim text.