Process for catalytically converting methanol to formaldehyde
AssigneeCelanese Corporation
InventorsCarl D. Murphy, William P. McMillan
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AssigneeCelanese Corporation
InventorsCarl D. Murphy, William P. McMillan
Estimating the term…
In catalytically oxidizing methanol in the vapor phase according to already-known processes for the production of formaldehyde, the hot formaldehyde-containing gaseous effluent of the catalytic converter is rapidly cooled by being passed through the tubes of a heat exchanger which are filled with balls composed of a solid which is substantially inert toward formaldehyde. As compared with a similar cooling system in which the tubes are empty or in which enhancement of heat transfer is attempted by using metal heat-transfer enhancement devices such as twisted metal ribbons, the present method affords reduced post-reaction decomposition of formaldehyde while at the same time allowing use of a relatively high temperature on the shell side of the heat exchanger whereby it becomes possible to raise steam at a pressure higher than that characteristic of the prior art.
In a process for converting methanol to formaldehyde, which process comprises (a) continuously passing a vaporous mixture comprising methanol and molecular oxygen through a converter containing a solid catalyst, (b) continuously converting at least a portion of the methanol in said vaporous mixture to formaldehyde in the presence of said catalyst, (c) continuously withdrawing from said converter a hot gaseous reaction product comprising formaldehyde at a temperature in the range of about 290.degree. C. to 700.degree. C., (d) continuously cooling said hot gaseous reaction product, and (e) processing the resulting cooled reaction product to recover a formaldehyde composition therefrom, the improvement which comprises:
Dependencies are inferred from the claim text.