Process for preparation of aqueous solutions of water-soluble polymers

An improved process for preparing dilute aqueous solutions of water-soluble polymer having an intrinsic viscosity of at least one deciliter per gram measured in 2 normal sodium chloride at 25.5.degree. C. from gels of said polymer, said process comprising the steps of:

• (a) extruding the water-soluble polymer gels into flowing water through die holes in an extrusion die plate, said die holes having diameters of from at least about 0.06 inch to about 0.50 inch, forming polymer gel strands,
• (b) cutting the extruding polymer gel strands at the exterior surface of the extrusion die plate to a length of less than about 0.75 inch, forming a slurry of the cut gel particles in the flowing water,
• (c) subjecting the slurry of gel particles of step (b) to high shearing forces immediately after formation of said slurry such that no substantial dissolution of the gel particles occurs prior to subjecting of said particles to said high shearing forces, said forces being sufficient to reduce the particle size of the cut gel particles to less than about 0.030 inch in greatest dimension, and
• (d) mixing the resultant slurry of fine gel particles and additional water under low shear conditions sufficient to maintain the suspension of particles in water, rapidly forming a dilute aqueous solution of polymer,
• the improvement in the extrusion step of said process, which comprises cutting the water soluble polymer gel, prior to feeding of the polymer gel to an extruder having a feed inlet, and an extruder screw having screw flights for the extruding of said polymer gel, into pieces of gel of a size which are at least containable within the volume of the extruder which can be defined between adjacent flights of the extruder screw at the feed inlet of said extruder and feeding the cut pieces of water soluble polymer gel to said extruder so that there is no substantial bridging of said polymer gel at the feed inlet of the extruder.