Asymmetric 1:2 metal complexes of diazo compounds
AssigneeSandoz Ltd.
InventorsHeinz Wicki, Claude Vogel
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AssigneeSandoz Ltd.
InventorsHeinz Wicki, Claude Vogel
Estimating the term…
1:2 Metal complexes of the formula ##STR1## in which each of X.sub.1 and X.sub.2, independently, is --COO-- or --O--, each of B.sub.1 and B.sub.2, independently, is a radical of a coupling component of the benzene or oxyquinoline series, M is a metal capable of forming a 1:2 complex and, each of ##STR2## independently, is the radical of a diazo component of the benzene series, with the proviso that at most one of such diazo component radicals contains a single sulpho group, and mixtures thereof with one or more of the corresponding symmetrical 1:2 metal complexes, which complexes and mixtures of complexes are in free acid or salt form and are useful as anionic dyes for dyeing and printing substrates such as natural and regenerated cellulose, natural and synthetic polyamides, polyurethanes and polymers modified to contain basic groups, especially leather.
A 1:2 metal complex of the formula ##STR47## said 1:2 metal complex being in free acid or salt form, wherein each of ##STR48## is independently the radical of a diazo component of the benzene series free from fiber-reactive groups, with the proviso that Rings A.sub.1 and A.sub.2 together contain a maximum of one sulfo group, each of B.sub.1 and B.sub.2 is independently the radical of a coupling component of the benzene or hydroxyquinoline series free from fiber-reactive groups, each of X.sub.1 and X.sub.2 is independently --COO-- or --O--, and M is a metal capable of forming a 1:2 metal complex.
A mixture of 1:2 metal complexes according to claim 28, said 1:2 metal complexes being in free acid or salt form, wherein each B.sub.1 ' and B.sub.2 ' is independently the radical of a coupling component of the formula ##STR83## wherein Y.sub.3 ' is hydrogen or methyl, with the proviso that when Y.sub.3 ' is methyl, it is ortho to at least one of the --NH.sub.2 groups.
Dependencies are inferred from the claim text.