Process for separation of indole using X and Y type zeolites
AssigneeAsahi Kasei Kogyo Kabushiki Kaisha
InventorsKenji Takasa, Keizo Hirakawa, Hiroji Nishimaru, Makoto Honda
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AssigneeAsahi Kasei Kogyo Kabushiki Kaisha
InventorsKenji Takasa, Keizo Hirakawa, Hiroji Nishimaru, Makoto Honda
Estimating the term…
A process for separating indole from a mixture of indole with at least one hydrocarbon or its derivative which comprises the steps of contacting the mixture with a faujasite structured zeolite to selectively adsorb indole on the zeolite and contacting a desorbent A selected from the group consisting of C.sub.2-10 aliphatic or C.sub.7-10 aromatic ether compounds, C.sub.2-10 aliphatic ester compounds and C.sub.3-10 aliphatic ketone compounds with the indole-adsorbed zeolite to separate indole and the process which comprises, in addition, the step of contacting at least one desorbent B of the formula, ##STR1## wherein R.sup.1 is a C.sub.1-3 alkyl group, and R.sup.2 is a hydrogen atom or a C.sub.1-3 alkyl group, with the indole-adsorbed zeolite prior to the contact of the desorbent A with the indole-adsorbed zeolite.
A process for separating indole from a mixture of indole with at least one compound selected from the group consisting of naphthalene, thionaphthene, 1-methylnaphthalene, 2-methylnaphthalene, biphenyl, 1,5-dimethylnaphthalene, 2,6-dimethylnaphthalene, acenaphthene, diphenylene oxide and fluorene which comprises the step of contacting the mixture with an X type zeolite whose exchangeable cation sites are occupied by at least one cation selected from the group consisting of lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, barium, copper, silver, zinc, cadmium, iron, nickel, cobalt and lanthanum ions or a Y type zeolite whose exchangeable cation sites are occupied by at least one cation selected from the group consisting of lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, barium, copper, silver, zinc, cadmium, iron, nickel, cobalt and lanthanum ions to selectively adsorb indole on the zeolite and contacting a desorbent A selected from the group consisting of C.sub.2-10 aliphatic ethers, C.sub.7-10 aromatic ethers, C.sub.2-10 aliphatic esters and C.sub.3-10 aliphatic ketones, with the indole-adsorbed zeolite to separate indole, the selectivity of the zeolite for indole over the desorbent A represented by K indole desorbent A ranging from 0.1 to 10.
Dependencies are inferred from the claim text.