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US 4,351,754 AGranted
Thickening agent for aqueous compositions
AssigneeRohm and Haas Company
InventorJean Dupre
Life of this patent
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Abstract
A mixture of a water swellable clay mineral and an alkali soluble and thickenable (meth)acrylic acid emulsion copolymer provides a highly effective thickening and gelling agent for aqueous systems at low concentrations. The gels are self-supporting and have high strength and thus are particularly useful as air fresheners and other applications where firm gels are desirable. A synergistic thickening effect between the (meth)acrylic acid copolymer and the clay mineral is observed.
Claims11
As a thickening agent for aqueous systems, a composition comprising a mixture of:
- (A) a water swellable clay mineral, and
- (B) a water insoluble emulsion polymer, an aqueous dispersion of which will thicken upon addition of a neutralization agent, of
- (1) 20-50 wt. % of (meth)acrylic acid,
- (2) 0.5-25 wt. % of at least one monomer of the formula (I):
- H.sub.2 C.dbd.C(R)--C(O)--O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.o
- wherein R is H or CH.sub.3, n is at least 2 and has an average value up to 60 or more, and R.sup.o is a group having at least 8 carbon atoms selected from alkyl, alkaryl and polycyclic hydrocarbyl,
- (3) at least 30 wt. % of an alkyl (meth)acrylate wherein the alkyl group has 1 to 4 carbon atoms, and
- (4) zero to 1.0 wt. % of a polyethylenically unsaturated monomer;
- the proportions of (A) and (B) being effective, upon addition of a neutralizing agent for (B), for thickening an aqueous dispersion formed therewith.
6 more elements
Dependencies are inferred from the claim text.