Insecticidal esters
AssigneeCommonwealth Scientific and Industrial Research Organization
InventorsGeorge Holan, David F. O'Keefe
Life of this patent
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AssigneeCommonwealth Scientific and Industrial Research Organization
InventorsGeorge Holan, David F. O'Keefe
Estimating the term…
Compounds of the general formula I ##STR1## wherein R.sup.1 is hydrogen or a methoxy, ethoxy, propoxy, butoxy, tetrafluoroethoxy, methylthio, ethylthio, propylthio, fluoro, chloro, bromo, methyl, ethyl, or nitro group, and R.sup.2 is hydrogen or a methyl group, or R.sup.1 and R.sup.2 together form a methylenedioxy group; R.sup.3 is hydrogen, or a lower alkyl group, or one of the following groups (a) to (f): (a) 3-phenoxybenzyl (b) 2-benzyl-4-furylmethyl (c) .alpha.-cyano-3-phenoxybenzyl (d) 3,4-methylenedioxybenzyl (e) .alpha.-ethynyl-3-phenoxybenzyl (f) .alpha.-cyano-3-(4'-chlorophenoxy)-benzyl and Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.5 and Y.sup.6 are the same or different groups and each is hydrogen or a fluoro, bromo or chloro group, with the proviso that when R.sup.1 is hydrogen, fluoro, chloro, bromo or methyl and R.sup.2 is hydrogen, then one of Y.sup.1 to Y.sup.6 is other than hydrogen. The compounds in which R.sup.3 is one of groups (a) to (f) are insecticides.
The (+), (-) and (.+-.) forms of the compounds of the general formula I ##STR9## wherein R.sup.1 is hydrogen, fluorine, chlorine, bromine, or a methoxy, ethoxy, propoxy, butoxy, tetrafluoroethoxy, methylthio, ethylthio, propylthio, methyl, ethyl, or nitro group, and R.sup.2 is hydrogen or a methyl group;
The (+), (-) and (.+-.) forms of 3'-phenoxybenzyl 1-(4-ethoxyphenyl)-2,2,3,3-tetrafluorocyclobutane-carboxylate.
The (+), (-) and (.+-.) forms of .alpha.-ethynyl-3'-phenoxybenzyl 1(4-ethoxyphenyl)-2,2,3,3-tetrafluorocyclobutane-carboxylate.
Dependencies are inferred from the claim text.