Catalytic reforming process
AssigneeExxon Research & Engineering Co.
InventorGeorge A. Swan
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AssigneeExxon Research & Engineering Co.
InventorGeorge A. Swan
Estimating the term…
A process, or procedure, for the start-up of reforming units, particularly those employing highly active sulfur-sensitive polymetallic, promoted noble metal containing catalysts. On start-up of a reforming unit, a sulfur-containing naphtha feed is fed at reforming conditions over a platinum-catalyst containing lead reactor of a series while bypassing subsequent reactors of the series, the product therefrom is separated into hydrogen-containing gas and C.sub.5.sup.+ liquid fractions, the hydrogen-containing gas fraction is desulfurized and dried and recycled to the platinum-catalyst containing lead reactor and, after sufficient hydrogen has been generated for operation of a Hydrofiner which is used to hydrodesulfurize the naphtha feed for the reformer, product from the platinum-catalyst containing lead reactor is fed to subsequent reactors of the series which contain the more sulfur-sensitive catalysts.
In a process for reforming a naphtha, with hydrogen, in a reforming unit which is a net producer of hydrogen, at least a portion of which is used in a Hydrofiner for hydrodesulfurizing the naphtha feed used in the reforming process, comprised of a plurality of serially connected reactors, inclusive of a lead reactor which contains a platinum catalyst and one or more subsequent reactors of the series which contains a sulfur sensitive metal promoted platinum catalyst, such that naphtha and hydrogen can be contacted with the platinum catalyst of the lead reactor at reforming conditions and the product of said reaction, and the products of subsequent reactions, passed in seratim from one reactor of the series to the next, the product of the final reactor of the series being separated into a hydrogen rich gaseous product and a C.sub.5.sup.+ liquid product with a portion of the gas being recycled to the lead reactor and another portion of the gas to said Hydrofiner,
Dependencies are inferred from the claim text.