Process for the dyeing of fibre material
AssigneeCiba-Geigy Corporation
InventorsDavid G. Evans, Jacques Zurbuchen, Willi Leutenegger
Life of this patent
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Abstract
An improved process for dyeing of fibre material, especially textile fibres, by applying to the fibre material at a temperature below the absorption temperature of the dyestuffs and with a goods-to-liquor ratio of 1:1.5 to 1:4, a concentrated aqueous dye liquor, said concentrated aqueous dye liquor containing at least one dyestuff which, in the case of the substrate to be dyed, has affinity to the fibres and which is either soluble or dispersible in water, and 0.2 to 10 g/l, preferably 2 to 5 g/l, of a surface-active agent, and finishing of the dyeing by means of a heat treatment, e.g. introduction of saturated steam, superheated steam or hot air, preferably by heating from without, at temperatures of 95.degree. to 140.degree. C.
Claims5
A batch process for the exhaustion dyeing of fiber material, comprising the steps of first applying to the fiber material an aqueous non-foaming dye liquor, containing no thickening agent and containing
- (a) a water-soluble or water-dispersible dyestuff having affinity for the fiber material and
- (b) a non-foaming amount, in the range of 0.2 to 10 grams per liter, of a surface-active agent which has no cloud point and which is selected from the group consisting of C.sub.10 to C.sub.20 -fatty acid soaps, sulfated C.sub.8 to C.sub.18 -alkanol soaps, sulfated unsaturated higher fatty acid ester soaps, soaps of sulfated ethyleneoxide-C.sub.8 to C.sub.20 -alkanol adducts, soaps of sulfated esterified polyoxy compounds, soaps of C.sub.8 to C.sub.20 -primary and secondary alkyl sulfonates, soaps of alkylarylsulfonates having at least 7 carbon atoms in the alkyl chain, soaps of sulfonates of polycarboxylic acid esters, soaps of sulfates of N-acylated alkanolamines, ethyleneoxide-higher fatty acid adducts, ethyleneoxide-C.sub.8 to C.sub.20 -alkanols, ethyleneoxide-C.sub.8 to C.sub.20 -mercaptan adducts, ethyleneoxide-C.sub.8 to C.sub.20 -amine adducts, ethyleneoxide-alkylphenol adducts wherein the alkyl radical contains at least 7 carbon atoms, ethyleneoxide-alkylthiophenol adducts wherein the alkyl radical contains at least 7 carbon atoms, fatty acid mono- or di-glycerides, higher molecular fatty acid amides, and adducts of higher molecular fatty acid-hydroxyalkyl amides with ethyleneoxide,
- at a goods-to-liquor ratio of 1:1.5 to 1:2.5 and at a temperature below the absorption temperature of the dyestuff, subsequently shaking or tossing the fiber material and applied aqueous dye liquor, in a closed container, sufficiently to evently distribute the aqueous dye liquor on the fiber material, while still maintaining the temperature below the absorption temperature of the dyestuff, and finally heating the fiber material and the evenly-distributed aqueous dye liquor at a temperature in the range of 95.degree. to 140.degree. C. to exhaust the dyestuff onto the fiber material.
Dependencies are inferred from the claim text.