Electrolytic cell for the production of aluminum
AssigneeMetallurgical, Inc.
InventorsJames C. Withers, Gary V. Upperman
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AssigneeMetallurgical, Inc.
InventorsJames C. Withers, Gary V. Upperman
Estimating the term…
A cell for the electrolytic deposition of aluminum at low temperatures and low electrical potential in which the anode is the sole source of aluminum and comprises a composite mixture of an aluminous material such as aluminum oxide and a reducing agent. Conductor means of higher electrical conductivity than the mixture are provided to conduct substantially the entire anodic current to the active anode surface thereby reducing the voltage drop through the highly resistive composite mixture. The mixture may be employed in a self-baking mode or be prebaked. Alternatively, the mixture may be in a particulate form and contained within a porous membrane which passes the electrolyte or other dissolved material while withholding undissolved impurities. The cell may have bipolar electrodes and may be used in combined winning and refining configurations.
An electrolytic cell for the production of aluminum comprising in combination, a housing having first and second compartments, a molten electrolyte containing ions selected from the group consisting of chlorides, fluorides or mixtures thereof in said compartments, a cathode in one of said compartments for the formation of molten metallic aluminum, an anode in the other of said compartments comprising an oxygen containing compound of aluminum in an amount sufficient to provide aluminum ions during electrolysis and a reducing agent in intermixed contact with said oxygen containing compound of aluminum, said electrolyte being of a material in which said compound will not readily dissolve in substantial quantities when the temperature of the electrolyte is in the range of 650.degree. to 900.degree. C., a porous membrane separating said first and second compartments, said membrane being of a material having a connected pore size sufficiently small to screen out said intermixture of said compound of aluminum and said reducing agent and sufficiently large to pass said aluminum ions, and a layer of impure aluminum forming a bipolar electrode disposed within said other compartment positioned between said anode and said cathode and supported by said membrane.
An electrolytic cell for the production of aluminum comprising in combination, a molten halide electrolyte containing aluminum ions and ions selected from the group consisting of chlorides, fluorides or mixtures thereof, a cathode for the formation of molten metallic aluminum, an anode for reaction within said electrolyte comprising an oxygen containing compound of aluminum in an amount sufficient to provide aluminum during electrolysis and a reducing agent in intermixed contact with said oxygen containing compound of aluminum and present in an amount sufficient to react at the anode site so as to produce aluminum ions in the electrolyte for reduction at the cathode into aluminum metal and constituting the sole source of input aluminum ore, said electrolyte being of a material in which said compound does not readily dissolve in substantial quantities when the temperature of said electrolyte is in the range of 650.degree. to 900.degree. C. to maintain said electrolyte relatively free of the dissolved compound of aluminum, an electrode positioned between said anode and cathode, said electrode being covered on one side only with said compound and said reducing agent and being in electrical contact with said compound of aluminum and said reducing agent for bipolar electrolysis.
An electrolytic cell for the production of aluminum comprising in combination,
Dependencies are inferred from the claim text.