Water-soluble disazo dyestuffs
AssigneeHoechst Aktiengesellschaft
InventorsErnst Hoyer, Fritz Meininger, Rudolf Fass
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AssigneeHoechst Aktiengesellschaft
InventorsErnst Hoyer, Fritz Meininger, Rudolf Fass
Estimating the term…
The novel water-soluble disazo dyestuffs consist of two monoazo dyestuff moieties each containing as diazo component an amine of the benzene or naphthalene series and as coupling component an amino-naphthol-mono- or disulfonic acid. The two moieties are bonded to each other via a bridge member bound to the amino groups of the coupling components and comprising two triazine radicals each containing a halogen atom, a sulfonic acid group or a thio ether or oxygen ether group or an amino group and the diazo components contain a fiber-reactive radical of the vinyl sulfone series. The metal-free dyestuffs can be transformed into the corresponding heavy metal complex dyestuffs, preferably copper, cobalt and chromium complex dyestuffs, by treatment with an agent donating a heavy metal cation. The novel dyestuffs are excellently suitable for dyeing and printing fiber material of natural and regenerated cellulose and natural, regenerated and synthetic polyamides. They are distinguished by a high tinctorial strength, a very good uptake from a long liquor, a good color- build up and good printing properties. The dyeings obtained therewith have a high fastness to processing and in use.
A water soluble dyestuff which in the form of the free acid has the formula (1) ##STR112## in which K.sub.1 and K.sub.2 are identical or different to each other and have in the form of the free acid, the formula ##STR113## in which R is hydrogen or alkyl and p is 1 or 2, K.sub.1 and K.sub.2 being bonded via the amino groups to the s-triazine radicals and bonded by the azo groups in ortho-position to their hydroxy groups, D is a benzene nucleus or naphthalene nucleus, R.sub.1 is in ortho-position to the azo group and is hydrogen, halogen, lower alkyl, lower alkoxy, hydroxy, carboxy or sulfo and R.sub.2 is hydrogen, halogen, lower alkyl, lower alkoxy, nitro or sulfo, R.sub.1 and R.sub.2 being identical or different from one another;
A dyestuff of the formula ##STR123##
A dyestuff of the formula ##STR124##
Dependencies are inferred from the claim text.