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US 4,319,974 AGranted
UV Curable compositions and substrates treated therewith
AssigneeGeneral Electric Company
InventorJames V. Crivello
Life of this patent
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Abstract
UV curable mixtures of C.sub.(8-28) .alpha.-olefin oxides and certain onium salt photoinitiators, for example, certain diaryliodonium salts, or triarylsulfonium salts, and optionally polyfunctional epoxy resin, have been found useful in paper release coating applications.
Claims4
Curable or polymerizable compositions comprising by weight
- (A) 15 to 100% of a C.sub.(8-12) .alpha.-olefin oxide,
- (B) 0 to 85% of a polyfunctional epoxy resin,
- (C) 0.1 to 10% based on the sum of the weight (A), (B) and (C) of an aryl onium salt of the formula,
- [Y].sup.+ [MQ.sub.n ].sup.-,
- where Y is a member selected from
- [(R).sub.a (R.sup.1).sub.b I] and
- [(R).sub.c (R.sup.2).sub.d (R.sup.3).sub.e S],
- where R is a monovalent aromatic organic radical, R.sup.1 is a divalent aromatic organic radical, R.sup.2 is a monovalent organic aliphatic radical selected from alkyl, cyano alkyl and substituted alkyl, R.sup.3 is a polyvalent organic radical forming a heterocyclic or fused ring structure, M is a metal or metalloid, Q is a halogen radical, a is a whole number equal to 0 or 2, b is a whole number equal to 0 or 1, and the sum of a+b is equal to 1 or 2, c is a whole number equal to 0 to 3 inclusive, d is a whole number equal to 0 to 2 inclusive, e is a whole number equal to 0 or 1, and the sum of c, d and e is equal to 1 to 3 inclusive, and n is an integer equal to 4-6 inclusive.
5 more elements
Dependencies are inferred from the claim text.