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US 4,318,845 AGranted
Alkanolamine esters of 1,1'-biphenyl-2,2'-diyl-and alkylidene-1,1'-biphenyl-2,2'-diyl-cyclic phosphites
AssigneeCiba-Geigy Corporation
InventorsJohn D. Spivack, Martin Dexter, Stephen D. Pastor
Life of this patent
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Abstract
The title compounds are prepared by reacting alkylated 1,1'-biphenyl-2,2'-diol or alkylated 2,2'-alkylidene-bis-phenol with phosphorus trichloride in an organic solvent and then reacting the intermediate phosphorochlorodite with an alkanolamine. Said phosphites are useful as stabilizers of organic polymers and lubricating oils, especially as processing stabilizers for polyolefins, elastomers, polyesters and polycarbonates.
Claims24
A compound of the formula ##STR20## wherein m, n and p are each 1, m is 2 and n is 1 and p is 0 or m is 3 and n and p are 0, and wherein
- R is alkyl of from 1 to 18 carbon atoms,
- R.sup.1 is hydrogen or alkyl of from 1 to 18 carbon atoms,
- R.sup.2 is a direct bond or alkylene of from 1 to 12 carbon atoms,
- A is alkylene of from 1 to 6 carbon atoms, or cycloalkylene of 5 to 6 carbon atoms,
- R.sup.3 is alkyl of 1 to 18 carbon atoms, or ##STR21## wherein Y is ##STR22## A' is alkylene of 1 to 6 carbon atoms or cycloalkylene of 5 to 6 carbon atoms,
- m' is 1 or 2,
- p is 0 or 1, and
- q is 0-5,
- with A, R, R.sup.1, R.sup.2 being as previously defined;
- provided that when p and q are 0, --N--A'--N can be a diazacycloalkyl group of 2 to 10 carbon atoms, or
- when m is 1 and p is 0, N--R.sub.3 is a azacycloalkyl group of 2 to 10 carbon atoms or an azaoxacycloalkyl group of 3 to 7 carbon atoms;
- and
- R.sup.4 is alkyl of 1 to 18 carbon atoms.
10 more elements
Dependencies are inferred from the claim text.