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US 4,315,855 AGranted
Monoazo disperse dyes containing a nitrophenyl group and a homophthalimide group
AssigneeBASF SE
InventorErnst Schefczik
Life of this patent
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Abstract
Dyes of the formula ##STR1## where X and Y, for example, can be hydrogen or halogen and R can be alkyl among other substituents. The dyes are derived from an O-nitroaniline diazo component and an N-substituted homophthalimide as coupling component. The dyes are greenish yellow to orange and give clear dyeings of good color strength and having good general fastness properties on polyesters, cellulose esters and in some cases also on polyamides. The fastness to light and the fastness to heat setting are excellent and may easily be influenced by the choice of substituents.
Claims1
An azo dye of the formula:
- ##STR136## in which Y.sup.1 is hydrogen, chlorine, carboalkoxy selected from the group consisting of carbomethoxy, carboethoxy, carbopropoxy, carbobutoxy, carbo-.beta.-ethylhexoxy, carbo-.beta.-hydroxyethoxy, carbo-.omega.-hydroxypentoxy, carbo-.omega.-hydroxyhexoxy, carbo-.beta.-methoxyethoxy and carbo-.beta.-butoxyethoxy or N-substituted carbamoyl selected from the group consisting of N-methylcarbamoyl, N-ethylcarbamoyl, N-propylcarbamoyl, N-butylcarbamoyl, N-.beta.-ethylhexylcarbamoyl, N-.beta.-hydroxyethylcarbamoyl, N-.beta.-hydroxypropylcarbamoyl, N-.gamma.hydroxypropylcarbamoyl, N-.beta.-methoxyethylcarbamoyl, N-.gamma.-methoxypropylcarbamoyl, N-.gamma.-butoxypropylcarbamoyl, N-.gamma.-(.beta.'-ethylhexoxy)-propylcarbamoyl, N,N-dimethylcarbamoyl, N,N-diethylcarbamoyl, N,N-dipropylcarbamoyl, N,N-dibutylcarbamoyl, N-methyl-N-.beta.-hydroxyethylcarbamoyl, N,N-di-.beta.-hydroxyethylcarbamoyl, N-benzylcarbamoyl, and N-phenylethylcarbamoyl;
- and
- R.sup.1 is selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, n-hexyl, .beta.-ethylhexyl, n-decyl, .beta.-methylnonyl, stearyl, .beta.-hydroxyethyl, .beta.-methoxyethyl, .gamma.-hydroxypropyl, .beta.-hydroxypropyl, .gamma.-methoxypropyl, .gamma.-ethoxypropyl, .gamma.-(.beta.-ethylhexoxy)-propyl, .gamma.-acetoxypropyl, .gamma.-propionyloxypropyl, benzoyloxyethyl, benzoyloxypropyl, methoxyacetoxypropyl, .alpha.-methyl-.beta.-hydroxypropyl, .beta.-methyl-.beta.-hydroxypentyl, .omega.-hydroxyhexyl, carboxymethyl or carboxypropyl, ethoxycarbonylmethyl, methoxycarbonylpropyl, dimethylaminocarbonylmethyl, butylaminocarbonylmethyl, phenylaminocarbonylpropyl, carboxyethyl, carboxypentyl, methoxycarbonylethyl, ethoxycarbonylpentyl, diethylaminocarbonylethyl, .beta.-ethylhexylaminocarbonylethyl, phenylaminocarbonylpentyl, acetylaminoethyl, propionylaminoethyl, acetylaminopropyl, acetylaminobutyl, propionylaminobutyl, benzoylaminobutyl, acetylaminohexyl, .omega.-cyanopentyl, .omega.-cyanohexyl, .beta.-(.beta.'-hydroxyethoxy)-ethyl, .beta.-(.beta.'-acyloxyethoxy)-ethyl and the radicals having the formulae:
- --C.sub.2 H.sub.4 S--C.sub.2 H.sub.4 OH, --C.sub.2 H.sub.4 S--C.sub.2 H.sub.4 OCOC.sub.6 H.sub.5, --C.sub.2 H.sub.4 SC.sub.2 H.sub.4 OCOC.sub.2 H.sub.5, ##STR137##
1 more element
Dependencies are inferred from the claim text.