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AssigneeHughes Aircraft Company
InventorsRicardo C. Pastor, Donald P. Devor
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The specification discloses a process for modifying the environment of active atoms in a selected material by removing impurities from the environment. The material is heated at an elevated temperature in an atmosphere conducive to the formation of atomic oxygen so that the atomic oxygen can react with the atoms and molecules in the environment to remove the impurities in and thus alter selected properties of the material. In a preferred embodiment of the present invention, the lasing efficiency of a neodymium-doped yttrium aluminum garnet crystal is increased by heating the crystal at an elevated temperature in an atmosphere conducive to the formation of atomic oxygen so that the atomic oxygen can react with and remove impurities from the crystal to diminish the color center concentration therein and thus increase the fluorescence yield and lasing efficiency of the crystal.
A process for modifying the environment of active atoms in a selected material by removing selected impurities from said environment, said impurities being selected from the group consisting of water and water-derived impurities and being substitutionally or interstitially incorporated in said material, which comprises heating said material at a predetermined elevated temperature in an atmosphere conducive to the formation of atomic oxygen for a period of time sufficient to enable said atomic oxygen to react with the atoms and molecules in said environment to thereby remove said impurities and alter selected properties of said material.
A process for increasing the lasing efficiency of a selected oxide laser material by removing selected impurities therein, said impurities being selected from the group consisting of water and water-derived impurities and being substitutionally or interstitially incorporated in said material, which comprises heating said material at a predetermined elevated temperature in an atmosphere conducive to the formation of atomic oxygen for a period of time sufficient to enable said atomic oxygen to react with and remove said impurities and to thereby increase said lasing efficiency.
A process for increasing the lasing efficiency of a Nd-doped laser host crystal selected from the group consisting of Y.sub.3 Al.sub.5 O.sub.12 (YAG), YAlO.sub.3 (YALO), Gd.sub.3 Ga.sub.5 O.sub.12 (GGG), YVO.sub.4, and Y.sub.2 O.sub.3, by diminishing the color center concentration therein, which comprises heating said crystal at a predetermined elevated temperature in an atmosphere conducive to the formation of atomic oxygen for a period of time sufficient to enable said atomic oxygen to react with and remove selected impurities from said crystal to diminish said color center concentration herein and thereby increase the fluorescence yield and lasing efficiency of said crystal.
A process for increasing the lasing efficiency of Nd-doped yttrium aluminum garnet (YAG) crystals which comprises heating said crystals at 1500.degree. C. or higher in a vapor mixture of chosen amounts of oxygen and iodine, which is conducive to the formation of atomic oxygen, for a period of time sufficient to enable said atomic oxygen to react with and remove water-derived impurities from said crystals and thereby increase the 1.06 micrometer fluorescence yield and lasing efficiency of said crystals.
A process for increasing the lasing efficiency of a Nd-doped laser host crystal selected from the group consisting of Y.sub.3 Al.sub.5 O.sub.12 (YAG), YAlO.sub.3 (YALO), Gd.sub.3 Ga.sub.5 O.sub.12 (GGG), YVO.sub.4, and Y.sub.2 O.sub.3 which comprises heating said crystal to a predetermined elevated temperature while exposing said crystal to atomic oxygen for a period of time sufficient to enable said atomic oxygen to react with and remove water-derived impurities from said crystal and thereby increase the 1.06 micrometer fluorescence yield and lasing efficiency of said crystal.
A Nd-doped laser host crystal selected from the group consisting of Y.sub.3 Al.sub.5 O.sub.12, YAlO.sub.3, Gd.sub.3 Ga.sub.5 O.sub.12, YVO.sub.4, and Y.sub.2 O.sub.3 having optimized lasing efficiency, formed by heating said crystal at a predetermined elevated temperature in an atmosphere conducive to the formation of atomic oxygen for a period of time sufficient to enable said atomic oxygen to react with and remove selected impurities from said crystal and thereby increase the fluorescence yield and lasing efficiency of said crystal.
A Nd-doped laser host crystal selected from the group consisting of Y.sub.3 Al.sub.5 O.sub.12, YAlO.sub.3, Gd.sub.3 Ga.sub.5 O.sub.12, YVO.sub.4, and Y.sub.2 O.sub.3, having optimized lasing efficiency, formed by heating said crystal to a predetermined elevated temperature while exposing said crystal to atomic oxygen for a period of time sufficient to enable said atomic oxygen to react with and remove water-derived impurities from said crystal and thereby increase the 1.06 micrometer fluorescence yield and lasing efficiency of said crystal.
Dependencies are inferred from the claim text.