Linear alpha olefin production

A process for producing alpha olefins in the range of about 4 to about 10 carbon atoms per molecule which comprises:

• (a) feeding ethylene which may be in part in a recycle system derived from a purification of the product of the process, and triethyl or tributyl or mixed tri(ethylbutyl) aluminum compound in the absence of any significant amount of product olefin in the range of 4 to 10 carbon atoms into a growth reaction system maintained at a temperature between about 100 and 140.degree. C. and a pressure of between about 400 to 800 psig for from about 5 to 90 minutes residence time wherein the ratio of C.sub.2 H.sub.4 to trialkylaluminum compound is at least 5 to 1, respectively,
• (b) separating the unreacted olefins from the trialkyl aluminum growth product,
• (c) displacing the alkyl moieties from the trialkyl aluminum growth product by contacting the growth product with C.sub.2 H.sub.4, C.sub.4 H.sub.8, or a mixture of C.sub.2 H.sub.4 and C.sub.4 H.sub.8 at a temperature of between about 200.degree. C. and 300.degree. C. for between about 0.1 to about 2.5 seconds residence time under elevated pressure 100 to 500 psig, thereby to displace the higher alkyl moieties of the trialkyl aluminum growth product and replace the displaced alkyl growth moieties with C.sub.2 H.sub.4 and C.sub.4 H.sub.8,
• (d) separating the .alpha.-olefin products obtained in the displacement step from the tri lower alkyl aluminum products produced on said displacement step,
• (e) returning the tri lower alkyl aluminum products to step (a),
• (f) separating the olefins in the gaseous effluent from said displacement products separation step (d),
• (g) separating the gaseous effluent into its component parts, including C.sub.2 H.sub.4 and C.sub.4 H.sub.8,
• (h) recycling the C.sub.2 H.sub.4 component to step (a) and/or step (c) and the C.sub.4 H.sub.8 to step (c), and
• (i) recovering the C.sub.4, C.sub.6, C.sub.8, and C.sub.10 .alpha.-olefins as product components.