Fiber lubricants yielding low residues upon oxidation
AssigneeBASF Wyandotte Corporation
InventorsBasil Thir, David D. Newkirk, Stephen E. Eisenstein, William K. Langdon
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Abstract
A linked compound is a useful lubricant for fibers such as nylon and polyester, providing low volatility at a temperature below about 230.degree. C. and by oxidizing, leaving a low level of residue, at temperatures above about 230.degree. C.
Claims23
A process of lubricating synthetic fibers which comprises applying to the fiber in an amount of from 0.05 weight percent to 5 weight percent, based on the weight of lubricated fiber, of a compound of the general formula:
- R(Z).sub.n (Y).sub.m (Z).sub.m-1 . . . H
- wherein R is HO or an alkoxy group having from 1 to 8 carbons in the alkyl chain;
- Z is a linker selected from the group consisting of ##STR5## wherein each R' is independently selected from methyl, ethyl, propyl, isopropyl or phenyl;
- Y is a polyoxyalkylene group made up from about 2 to x units wherein each unit is selected individually, in heteric or block mixtures thereof from oxyethylene, oxypropylene, oxybutylene, and oxytetramethylene;
- x is a number selected such that the approximate average molecular weight contribution of the polyoxyalkylene group is from about 100 to about 800;
- m is a number from 2 to 40;
- n is 1 or 0, with the proviso that when R is HO, n equals 0, with the further proviso that the Z groups can be coupled to the Y groups either in a heteric or block arrangement, and with the proviso that a unit of Z is not directly attached to the terminal H.
A nylon or polyester fiber coated with a fiber lubricant comprising a condensation product of formaldehyde and an alkylene glycol, an alkylene oxide adduct thereof, and mixtures thereof, in which the alkylene radicals contain from 2 to 3 carbon atoms, said condensation product being present in an amount of from 0.05 weight percent to 5 weight percent based on the weight of lubricated fiber and such lubricant showing a volatility at a temperature of approximately 230.degree. C. below 10 weight percent loss based on the weight of fiber lubricant and yielding a level of residue of less than two weight percent based on the weight of the fiber lubricant upon oxidation at the heater plate temperature.
Dependencies are inferred from the claim text.