Recovery of catalysts
AssigneeUop LLC
InventorMichael H. Quick
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Abstract
Metal catalyst complexes such as those containing a metal of Group VIII of the Periodic Table which have been used in organic reactions such as the hydroformylation of olefins to form alcohols may be recovered from the product alcohols by treating said alcohol with anhydrous gaseous ammonia at temperatures in the range of from about 0.degree. to about 100.degree. C. and pressures in the range of from about 5 to about 1000 psi to precipitate the solution catalyst complex and thereby enable the separation of the catalyst complex from the product to be accomplished in a relatively simple manner.
Claims11
A process for the recovery of cobalt, rhodium or ruthenium metal complex catalyst from a liquid hydroformylation alcohol reaction product obtained from treatment of an olefinic hydrocarbon with hydrogen and carbon monoxide in the presence of said cobalt, rhodium or ruthenium metal complex catalyst at hydroformylation conditions comprising a temperature in the range of from about 50.degree. to about 250.degree. C. and a pressure in the range of from about 50 to about 300 atmospheres, which recovery process comprises treating said hydroformylation alcohol reaction product with an effective amount of gaseous anhydrous ammonia at a temperature in the range of from about 0.degree. to about 100.degree. C. and a pressure in the range of from about 5 to about 1000 p.s.i. to precipitate said cobalt, rhodium or ruthenium metal complex catalyst, separating said precipitated cobalt, rhodium or ruthenium solid metal complex catalyst precipitate from said hydroformylation alcohol reaction product, and recovering said cobalt, rhodium or ruthenium solid metal complex catalyst.
Dependencies are inferred from the claim text.