Process and apparatus for catalytic hydrocarbon conversion
AssigneeInstitut Francais du Petrole
InventorYves Jacquin
Life of this patent
Estimating the term…
Abstract
A catalytic process for the conversion of hydrocarbons or bituminous shales or carbon monoxide in the liquid phase in contact with hydrogen flowing upwardly through a series of successive stages, each containing a catalyst bed either semi-stationary or dispersed in the charge, the catalyst being maintained at each stage by an upward flow of hydrogen or hydrocarbon supplied below an opening in the partition wall between two successive stages and periodically allowed to pass from one stage to the next through said opening, by discontinuing said upward flow.
Claims10
A liquid phase process for the catalytic conversion of hydrocarbons or carbon monoxide in the presence of hydrogen, consisting essentially of passing a liquid phase and a hydrogen-containing main gas stream upwardly through at least one catalytic reaction zone comprising several superposed stages, the at least one catalytic reaction zone containing a catalyst bed in each stage which may be either a semi-stationary bed or an ebullated bed, at least one intermediary stage being in permanent communication respectively with the next lower stage and with the preceding upper stage, through a perforated support having multiple openings having small cross-sections of a size smaller than the catalyst particles, and through respective at least one opening having large cross-sections substantially larger than the catalyst particles, the large cross-section openings adapted to allow periodical passage of the catalyst from one stage to another, the process comprising periodically injecting at least one fluid selected from hydrogen, a hydrogen-containing gas and a liquid hydrocarbon, upwardly, from below said openings of relatively large cross-section, at a flow rate and a velocity sufficient to substantially slow down or impede the passage of the catalyst from one stage to the next lower stage through said openings of relatively large cross-section, and periodically discontinuing the injection, or periodically reducing the injection flow rate from below at least one of said openings of relatively large cross-section, to allow passage of the catalyst, downwardly through said at least one of said openings of relatively large cross-section from one stage to the next lower stage.
In a liquid phase process for the catalytic conversion of hydrocarbons or carbon monoxide in the presence of hydrogen, comprising the passing of a liquid phase and a hydrogen containing main gas stream upwardly through at least one catalytic reaction zone comprised of several superposed stages, each stage containing a catalyst bed of either a semi-stationary bed type or an ebullated bed type, at least one intermediate stage being in permanent communication respectively with both the next lower stage and with the preceding upper stage through:
- (a) a perforated support having multiple openings having small cross sectional areas of a size smaller than the catalyst particles, and (b) through at least one opening of large cross-section substantially larger than the catalyst particles, the improvement comprising the steps of:
- periodically injecting at least one fluid selected from a hydrogen-containing gas and a liquid hydrocarbon, upwardly through said at least one opening of large cross-section, at a flow rate sufficient to substantially impede the passage of catalyst from each upper stage to the next lower stage through said at least one opening of large cross-section;
- and
- periodically reducing the injection flow rate of said at least one fluid sufficient to allow passage of the catalyst through said at least one opening of large cross-section, whereby substantially only relatively less active catalyst is removed from the catalytic reaction zone while maintaining relatively more active catalyst therein.
Dependencies are inferred from the claim text.