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US 4,309,358 AGranted
Agricultural stannanamines
AssigneeE. I. Du Pont de Nemours and Company
InventorCaleb W. Holyoke, Jr.
Life of this patent
Estimating the term…
Abstract
N,N-diaryl stannanamines such as 1,1,1-tributyl-N-[2-chloro-5-(trifluoromethyl)phenyl]-N-[2,4-dinitro-6-(tr ifluoromethyl)phenyl] stannanamine are useful as miticides, insecticides, fungicides, ovicides and herbicides.
Claims15
A compound of the formula ##STR10## wherein Z.sub.1, Z.sub.2 and Z.sub.3 are independently C.sub.1 -C.sub.8 allyl, C.sub.5 -C.sub.6 cycloalkyl or phenyl;
- R.sub.1, R.sub.3 and R.sub.4 are independently H, F, Cl, Br, NO.sub.2, CF.sub.3, OCF.sub.2 H, OCF.sub.3, OCF.sub.2 CF.sub.2 H or S(O).sub.k R.sub.9 ;
- and
- R.sub.3 and R.sub.4 can be taken together to form --OCF.sub.2 O-- or --OCF.sub.2 OCF.sub.2 --;
- R.sub.2 is H, F, Cl, Br, NO.sub.2, CF.sub.3 or S(O).sub.k R.sub.9 ;
- R.sub.5 is H, Cl, F, Br or NO.sub.2 ;
- R.sub.6 is H, NO.sub.2 or CF.sub.3 ;
- R.sub.7 is NO.sub.2 or CF.sub.3 ;
- k is 0, 1 or 2;
- R.sub.9 is C.sub.1 -C.sub.2 alkyl, optionally substituted with 2-4 Cl or F
- provided that
- (1) at least two of R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are hydrogen;
- (2) no more than two of the substituents R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are simultaneously NO.sub.2 or CF.sub.3 ;
- (3) when two NO.sub.2 or two S(O).sub.k R.sub.9 groups are present they are not ortho to one another, and further provided that when R.sub.6 is NO.sub.2, then
- (a) R.sub.1 is H, F or Cl when R.sub.3 or other than H, F, or Cl;
- (b) when R.sub.1 =R.sub.3 =R.sub.5, then R.sub.1, R.sub.3 and R.sub.5 are either H or F;
- and
- (c) R.sub.5 is either H or F.
14 more elements
Dependencies are inferred from the claim text.