Preparation of bisphenols
AssigneeShell Oil Company
InventorArien Kwantes
Life of this patent
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Abstract
An improved continuous process for preparing bisphenols from phenols and carbonyl compounds in the presence of an acidic ion-exchange resin is described. The improvement comprises recycling a portion of the stream containing bisphenol to the reaction zone before the bisphenol is recovered therefrom.
Claims8
A continuous process for the preparation of 2,2-bis(4-hydroxyphenyl)propane comprising reacting, in a reaction zone, at a temperature from about 30.degree. to about 120.degree. C., at least two moles of phenol with acetone in the presence of an acid ion-exchange resin having an exchange capacity of at least 2.0 meq H+/g of dry resin, separating the reaction zone effluent into two streams, the first stream comprising unreacted acetone, water and phenol and the second stream comprising 2,2-bis(4-hydroxyphenyl)propane, reaction by-products and phenol and recovering 2,2-bis(4-hydroxyphenyl)propane from the second stream, wherein a part of the second stream is recycled to the reaction zone before the 2,2-bis(4-hydroxyphenyl)propane is recovered therefrom.
Dependencies are inferred from the claim text.