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US 4,308,357 AGranted
Block copolymerization process and product
AssigneeEl Paso Polyolefins Company
InventorsMalcolm J. Kaus, Birendra K. Patnaik
Life of this patent
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Abstract
A process for the preparation of ethylene-propylene block copolymers at high catalyst productivity rates resulting in polymer products having improved impact strength-polymerized ethylene content relationship.
Claims24
A block copolymerization process for the production of impact resistant ethylene-propylene block polymers at high productivity rates, which comprises
- I. in a first stage producing a propylene prepolymer in the presence of no more than about 5 vol % of inert diluents by polymerizing propylene at pressures sufficient to maintain propylene in liquid phase, at a residence time of about 30 minutes or below and at temperatures between about 115.degree. F. and about 165.degree. F. in the presence of a catalyst composition containing the components
- (a) an aluminum trialkyl or an aluminum trialkyl at least partially complexed with an electron donor compound, and
- (b) titanium tri- or tetrahalide supported on magnesium dihalide, or a complex of a titanium tri- or tetrahalide with an electron donor compound supported on magnesium dihalide, the components (a) and (b) being provided in a molar ratio of Al/Ti between about 10 and about 400;
- II. in a second stage contacting the prepolymer of the first stage with a monomer mixture of ethylene and propylene at a pressure sufficient to maintain propylene in liquid phase, at a temperature between about 115.degree. F. and about 165.degree. F., a residence time of between about 30 and about 450 minutes in the substantial absence of inert diluents, and
- III. separating the product of Step II from the unreacted monomer.
2 more elements
Dependencies are inferred from the claim text.