Silver halide photographic emulsion
AssigneeFuji Photo Film Co., Ltd.
InventorsMasanao Hinata, Haruo Takei, Akira Sato, Atsuo Iwamoto, Jun Hayashi
Life of this patent
Estimating the term…
Loading patent…
AssigneeFuji Photo Film Co., Ltd.
InventorsMasanao Hinata, Haruo Takei, Akira Sato, Atsuo Iwamoto, Jun Hayashi
Estimating the term…
A silver halide photographic emulsion selectively spectrally sensitized, particularly to red light, with a combination of at least one sensitizing dye represented by general formula (I): ##STR1## wherein Z.sup.1 and Z.sup.2 each represents the atoms necessary to form a benzothiazole nucleus or a benzoselenazole nucleus, R.sup.1 and R.sup.2 l each represents an alkyl group or a substituted alkyl group, wherein at least one of R.sup.1 or R.sup.2 should represent a sulfo group-containing substituted alkyl group, a carboxyalkyl group or a hydroxyalkyl group, R.sup.3 represents an alkyl group, X.sub.1 represents an acid anion, and m represents 1 or 2, wherein m equals 1 when the dye forms an intramolecular salt (betaine-like structure); at least one sensitizing dye represented by general formula (II): ##STR2## wherein Z.sup.3 represents a sulfur atom or a selenium atom, Z.sup.4 represents the atoms necessary to form a benzothiazole nucleus, a benzoselenazole nucleus, a naphtho[1,2-d]thiazole nucleus or a naphtho[1,2-d]selenazole nucleus, R.sup.4 and R.sup.5 each represents an alkyl group or a substituted alkyl group, wherein at least one of R.sup.4 or R.sup.5 should be a sulfo group-containing substituted alkyl group, a carboxyalkyl group or a hydroxyalkyl group, R.sup.6 represents an alkyl group, an aryl group, a furyl group or a thienyl group, X.sub.2 represents an acid anion, and n represents 1 or 2, wherein n equals 1 when the dye forms an intramolecular salt (betaine-like structure), and at least one benzimidazolothiacarbocyanine dye, which exhibits increased color reproducibility, high sensitivity and reduced residual coloration.
A silver halide photographic emulsion spectrally sensitized with a combination of at least one sensitizing dye represented by the following general formula (I):
A photographic silver halide emulsion spectrally sensitized with a sensitizing combination of at least one sensitizing dye represented by formula (I), at least one sensitizing dye represented by formula (II), and at least one sensitizing dye represented by formula (III):
Dependencies are inferred from the claim text.