Use of chloro-hydrocarbons to produce high density electrodes
AssigneeGreat Lakes Carbon Corporation
InventorKenneth W. Tucker
Life of this patent
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Abstract
Chloro-hydrocarbons are used as pitch binder modifiers to improve the strength, density and electrical properties of carbon and graphite articles produced from carbonaceous particles, binders, and additives, and are particularly useful in manufacture of electrodes used in ultra high powered electric arc steel furnaces.
Claims9
In a carbon article manufactured by the process of mixing carbonaceous particles selected from the group consisting of calcined needle coke, coal coke, coal tar residue coke, calcined anthracite, graphite, graphitized aggregate and pre-grahitized coke and a carbonaceous binder selected from the group consisting of petroleum pitch, coal tar pitch, phenolic resin, furfural resin and lignosulfonates in a liquid form, shaping the resulting mixture by extrusion or molding to form said article, and baking said article to approximately 800.degree. to 900.degree. C., to carbonize said binder, the improvement comprising employing as an additive to said mixture a material selected from the group consisting of the chlorinated derivatives of naphthalene with from four to eight atoms of chlorine substituted for hydrogen atoms on said naphthalene molecules, known as the tetra, penta, hexa, hepta, and octachloro derivatives of naphthalene or mixtures of same.
An electrode suitable for use in an ultra high powered electric arc steel furnace manufactured from a mixture comprising needle coke particles having a coefficient of thermal expansion of less than 5.times.10.sup.-7 cm/cm/.degree. C. over the range of 0.degree. to 50.degree. C., and a coal tar pitch binder, the improvement comprising the use of from 0.25 to 2 parts by wt. of an additive to 100 parts by wt. of said particles, selected from the group consisting of the chlorinated derivatives of naphthalene having four or more chlorine atoms per molecule of naphthalene, the tetra, penta, hexa, hepta, and octachloronaphthalenes or mixtures of said chlorinated derivatives of naphthalene, as a polymerization accelerator for said pitch binder.
Dependencies are inferred from the claim text.