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US 4,308,074 AGranted
Precipitated silicic acid, method and compositions containing same
AssigneeDeutsche Gold- und Silber-Scheideanstalt vormals Roessler
InventorsPeter Nauroth, Heinz Esch, Robert Kuhlmann, Rudolf Bode, Arthur Reisert, Harald Buhler, Gunter Turk
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Abstract
Finely divided precipitated silicic acid is obtained by the method of the invention. Compositions containing the finely divided precipitated silicic acid as a filler distributed in an elastomer such as an organopolysiloxane are disclosed.
Claims2
A process for the production of hydrophobic silicic acid comprising treating precipitated silicic acid having the following properties:
- ______________________________________ BET surface acc. to DIN 66 131 m.sup.2 /g 150 .+-. 30 Average size of the primary particles from EM pictures nm 15-22 Loss after drying acc. to DIN 55 921 after 2 hours at 105.degree. C. % 2.5-3.5 Loss at red heat (related to the substance dried for 2 hours at 105.degree. C.) acc. to DIN 55 921 % 3 .+-. 0.5 pH value (in 5% aqueous dis- persion) acc. to DIN 53 200 3.5-5.5 Conductivity (in 4% aqueous dispersion) us <500 Tamped density of the unaerated substance acc. to g/l 60 .+-. 20 DIN 53 194 SO.sub.3 content (related to the substance dried for 2 hours at 105.degree. C.) % <0.3 Na.sub.2 O content (related to the substance dried for 2 hours at 105.degree. C.) % <0.3 ______________________________________
- with a hydrophobic agent in a ratio of 10:0.5 to 10:3 and agitating the precipitated silicic acid with hydrophobic agent, and tempering the product obtained for 60 to 180 minutes at a temperature of 200.degree. C. to 400.degree. C. and thereafter grinding to form a finely divided product.
Dependencies are inferred from the claim text.