Process for the production of polyurethane silicate foams and resinous products utilizing aldehyde-broken down alkali metal cellulose silicate polymer
OwnerDavid H. Blountinventor
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Abstract
Organic polyisocyanates are reacted chemically with aldehyde-broken down alkali metal cellulose silicate polymers to produce polyurethane products.
Claims15
The process for the production of polyurethane silicate foam by the following steps:
- (a) mixing and reacting 1 to 99 parts by weight of aldehyde-broken down alkali metal cellulose silicate copolymer, which is produced by heating a mixture of 3 parts by weight of a cellulose-containing plant, 2 to 5 parts by weight of an alkali metal hydroxide and 1 to 2 parts by weight of an oxidated silicon compound to 150.degree. to 220.degree. C. while agitating for 5 to 60 minutes thereby producing a broken down alkali metal cellulose silicate polymer which is then reacted with an aldehyde in ratio of 2 parts by weight of the broken down alkali metal cellulose silicate polymer to 1 to 5 parts by weight the aldehyde to produce the aldehyde-broken down cellulose silicate copolymer, and 50 to 99 parts by weight of an organic polyisocyanate thereby producing an isocyanate-terminated polyurethane silicate prepolymer,
- (b) mixing and reacting up to 10% by weight of an initiator with the isocyanate terminated polyurethane silicate prepolymer thereby producing a polyurethane silicate foam.
The process of claim 1 wherein 1 to 50 parts by weight of a polyol, 1 to 50 parts by weight of a curing agent, up to 50% by weight of a blowing agent, boiling within the range of from -25.degree. to 80.degree. C., up to 5% by weight of an emulsifier, up to 10% by weight of an initiator and up to 20% by weight of a foam stabilizer, percentage are based on the weight of the reactants are added and reacted in step (a) of claim 26 thereby producing a polyurethane silicate foam.
Dependencies are inferred from the claim text.