Plural imaging component microcellular arrays, processes for their fabrication, and electrographic compositions
AssigneeEastman Kodak Company
InventorsRichard N. Blazey, Peter S. Alexandrovich, Domenic Santilli, Michael W. Mosehauer
Life of this patent
Estimating the term…
Abstract
A planar array of microcells is formed in a support. An electrostatic charge pattern is established on the support differentiating first and second interlaid sets of microcells. An electrographic imaging composition is introduced into the first set of microcells, and a second, differing imaging composition is introduced into the second set of microcells. Multicolor photographic elements, particularly dye image transfer photographic elements, can be prepared.
Claims40
In a process comprising
- forming in a support having first and second major surfaces a planar array of microcells opening toward the first major surface and
- selectively introducing a first imaging composition into a first set of microcells, and a second, differing imaging composition into a second set of microcells forming an interlaid pattern with the first set of microcells,
- the improvement comprising
- establishing an electrostatic charge pattern on the support differentiating the first and second sets of microcells and
- selectively introducing an electrographic first imaging composition into the first set of microcells.
A process comprising
- applying an electrostatic charge in a nonimagewise manner to a photoconductive portion of a support means, the support means having first and second major surfaces and the photoconductive portion defining microcells opening toward the first major surface to form a planar array,
- selectively altering the electrostatic charge associated with a first set of microcells in relation to remaining, interlaid microcells,
- selectively introducing an electrographic imaging composition into the first set of microcells, and
- introducing a second imaging composition into at least a portion of the remaining microcells.
A process comprising
- applying an electrostatic charge in a nonimagewise manner to a photoconductive portion of a support means, the support means having first and second major surfaces and the photoconductive portion defining microcells opening toward the first major surface to form a planar array,
- addressing a first set of microcells with radiant energy to which the photoconductive portion is responsive to selectively remove electrostatic charge,
- selectively introducing a first electrographic imaging composition into the first set of microcells,
- reapplying an electrostatic charge in a nonimagewise manner to the photoconductive portion of the support means,
- addressing a second set of microcells and at least a portion of the first set of microcells with radiant energy to which the photoconductive portion is responsive to selectively remove electrostatic charge, the second set of microcells forming an interlaid pattern with the first set of microcells, and
- introducing a second electrographic imaging composition into the second set of microcells while excluding the second electrographic imaging composition from the first set of microcells.
In a process comprising
- forming in a support having first and second major surfaces a planar array of microcells opening toward the first major surface and
- selectively introducing (1) a first imaging composition comprised of a substantially immobile first additive primary colorant means and a complementary subtractive primary dye or dye precursor into a first set of microcells, (2) a second imaging composition comprised of a substantially immobile second additive primary colorant means and a complementary subtractive primary dye or dye precursor into a second, interlaid set of microcells, and (3) a third imaging composition comprised of a substantially immobile third additive primary colorant means and a complementary subtractive primary dye or dye precursor into a third, interlaid set of microcells
- the improvement comprising
- establishing an electrostatic charge pattern on the support differentiating the first and remaining sets of microcells.
- selectively introducing an electrographic first imaging composition into the first set of microcells,
- differentiating the second and third sets of microcells in the electrostatic charge associated therewith,
- selectively introducing an electrographic second imaging composition into the second set of microcells, and
- introducing the third imaging composition into the third set of microcells.
In an element comprising
- support means having first and second major surfaces defining microcells opening toward said first major surface to form a planar array,
- two or more differing imaging compositions each located in a separate interlaid set of microcells,
- the improvement comprising
- said support including a photoconductive portion defining the microcells and
- at least one of said imaging compositions being electrographic.
An element comprising
- support means having first and second major surfaces including a photoconductive portion defining microcells opening toward said first major surface to form a planar array,
- the microcells being separated by lateral walls and having bottom walls formed by the photoconductive portion,
- three differing imaging compositions each located in a separate interlaid set of microcells, and
- at least two of the imaging compositions being electroscopic.
A photographic element comprising
- support means having first and second major surfaces including a photoconductive portion defining microcells opening toward said first major surface to form a planar array,
- said support means providing a lateral barrier between adjacent microcells,
- a segmented blue filter means located in a first set of the microcells,
- a segmented green filter means located in a second set of the microcells,
- a segmented red filter means located in a third set of the microcells,
- the first, second, and third sets of the microcells forming an interlaid pattern of blue, green, and red filter segments, and
- radiation-sensitive imaging means positioned adjacent said first major surface of said support means.
A photographic element comprising
- support means having first and second major surfaces including a photoconductive portion defining microcells opening toward said first major surface to form a planar array, said support means being impermeable to aqueous alkaline processing solution and forming transparent bottom walls of the microcells and light absorbing lateral walls providing a barrier between adjacent microcells,
- an immobile blue filter and a yellow dye or dye precursor capable of shifting between a mobile and an immobile form as a function of silver halide development located in a first set of the microcells,
- an immobile green filter and a magenta dye or dye precursor capable of shifting between a mobile and an immobile form as a function of silver halide development located in a second set of the microcells,
- an immobile red filter and a cyan dye or dye precursor capable of shifting between a mobile and an immobile form located in a third set of the microcells,
- the first, second, and third sets of microcells forming an interlaid pattern,
- a transparent cover sheet overlying said first major surface of said support means,
- radiation-sensitive silver halide located between said support means and said transparent cover sheet,
- a dye immobilizing means located adjacent said cover sheet,
- reflective pigment means for providing a reflective surface underlying said dye immobilizing means,
- an aqueous alkaline processing solution, and
- means for initially confining and thereafter releasing said aqueous alkaline processing solution at a location between said support means and said cover sheet.
An electrographic imaging composition comprising
- a colorant portion comprised of one or more immobile colorants collectively capable of producing an additive primary color and a complementary subtractive primary dye or dye precursor capable of shifting between a mobile and an immobile form as a function of silver halide development,
- from 0.1 to 10 parts by weight per part of the colorant portion of a resinous portion capable of forming a particulate dispersion with the colorant portion in a liquid carrier vehicle having a dielectric constant of less than 3.0 and a resistivity of at least 10.sup.10 ohm-cm, and
- at least one of said colorant and resinous portions being chosen to impart an electrostatic charge of a selected polarity to the particulate dispersion in the liquid carrier.
An electrographic imaging composition comprising
- a colorant portion comprised of one or more immobile pigments collectively capable of imparting a blue color to the composition and a yellow dye or dye precursor capable of shifting between a mobile and an immobile form as a function of silver halide development, and
- from 0.3 to 3.0 parts by weight per part of the colorant of a resinous portion capable of forming a particulate dispersion with the colorant portion in a liquid hydrocarbon having dielectric constant of less than 3.0 and a resistivity of at least 10.sup.10 ohm-cm, the binder portion including a charge control agent in an amount sufficient to impart an electrostatic charge of a positive polarity to the particulate dispersion in the liquid hydrocarbon.
An electrographic imaging composition comprising
- a colorant portion comprised of one or more immobile pigments collectively capable of imparting a green color to the composition and a magenta dye or dye precursor capable of shifting between a mobile and an immobile form as function of silver halide development,
- from 0.3 to 3.0 parts by weight per part of the colorant of a resinous portion capable of forming a particulate dispersion with the colorant portion in a liquid hydrocarbon having a dielectric constant of less than 3.0 and a resistivity of at least 10.sup.10 ohm-cm, the resinous portion including a charge control agent in an amount sufficient to impart an electrostatic charge of a positive polarity to the particulate dispersion in the liquid hydrocarbon.
An electrographic imaging composition comprising
- a colorant portion comprised of one or more immobile pigments collectively capable of imparting a red color to the composition and a yellow dye or dye precursor capable of shifting between a mobile and an immobile form as a function of silver halide development,
- from 0.3 to 3.0 parts by weight per part of the colorant of a resinous portion capable of forming a particulate dispersion with the colorant portion in a liquid hydrocarbon having a dielectric constant of less than 3.0 and a resistivity of at least 10.sup.10 ohm-cm, the resinous portion including a charge control agent in an amount sufficient to impart an electrostatic charge of a positive polarity to the particulate dispersion in the liquid hydrocarbon.
Dependencies are inferred from the claim text.