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US 4,306,992 AGranted
Vulcanization system, a rubber mixture containing this vulcanization system and a vulcanization process
AssigneeBayer Aktiengesellschaft
InventorsRudiger Schubart, Ulrich Eholzer, Theo Kempermann, Ernst Roos
Life of this patent
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Abstract
A mixture comprising sulphur or a sulphur donor, a mercapto- or sulfenamide vulcanization accelerator, a compound containing a thiophenyl radical and a standard auxiliary accelerator is used as a vulcanization system for natural or synthetic rubber.
Claims2
A vulcanization system comprising
- (A) from 20 to 50 parts by weight of sulfur or a sulfur donor,
- (B) from 20 to 50 parts by weight of a mercapto or sulfenamide accelerator,
- (C) from 0 to 10 parts by weight of a conventional auxiliary accelerator and
- (D) from 20 to 50 parts by weight of a compound selected from the group consisting of ##STR6## wherein R.sub.1 taken separately is hydrogen, C.sub.1 -C.sub.10 alkyl or alkenyl, C.sub.5 -C.sub.7 cycloalkyl or cycloalkenyl, C.sub.6 -C.sub.10 aryl, or C.sub.6 -C.sub.10 aryl substituted at least once by alkyl having 1 to 4 carbon atoms;
- R.sub.2 taken separately is hydrogen, C.sub.1 -C.sub.10 alkyl or alkenyl, C.sub.5 -C.sub.7 cycloalkyl or cycloalkenyl, C.sub.6 -C.sub.10 aryl, C.sub.6 -C.sub.10 aryl substituted at least once by alkyl having 1 to 4 carbon atoms, a radical of the formula ##STR7## or a radical of the formula ##STR8## n is 2 or 3 n.sub.1, n.sub.2 and n.sub.3 are each a number from 2 to 10;
- R.sub.1 and R.sub.2 taken together form a 4- to 10-member carbocyclic ring or one of said rings containing N, O or S as a hetero atom;
- R.sub.3 to R.sub.7 are each hydrogen, halogen, nitro, cyano, --CF.sub.3, --CCl.sub.3, alkoxy carbonyl having 2 to 5 carbon atoms or C.sub.1 -C.sub.4 alkyl with the proviso that at least one of R.sub.3 -R.sub.7 is other than hydrogen;
- R.sub.8 is hydrogen or methyl and
- R.sub.9 is C.sub.4 -C.sub.12 cycloalkyl, C.sub.6 -C.sub.10 aryl, di-C.sub.4 -C.sub.12 cycloalkyl substituted C.sub.1 -C.sub.4 alkyl, tri-C.sub.4 -C.sub.12 cycloalkyl substituted C.sub.1 -C.sub.4 alkyl, di-C.sub.6 -C.sub.10 aryl substituted C.sub.1 -C.sub.4 alkyl or tri-C.sub.6 -C.sub.10 aryl substituted C.sub.1 -C.sub.4 alkyl.
6 more elements
Dependencies are inferred from the claim text.