Hydroxybenzophenones
AssigneeCarstab Corporation
InventorsKenneth R. Molt, Thomas G. Kugele, Karl R. Wursthorn
Life of this patent
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Abstract
The storage stability of impure hydroxybenzophenones is improved by the addition thereto of an organic phosphite or organic phosphonite.
Claims11
A polymer free composition comprising a color unstable substituted or unsubstituted 2-hydroxybenzophenone and a phorsphorus containing compound selected from the group consisting of organic phosphite and organic phosphonite wherein the substituted and unsubstituted 2-hydroxybenzophenone is given by the following formula. ##STR5## wherein:
- R.sup.1 and R.sup.4 are the same or different and are selected from the group consisting of (1) hydrogen and (2) unsubstituted and substituted alkyl, aryl, alkaryl, aralkyl, alkenyl or cycloalkyl group wherein the substitutent is halogen,
- R.sup.2 and R.sup.3 are the same or different and are selected from the group consisting of R.sup.1, Br, Cl and alkoxy,
- a is 0, 1 or 2,
- b is 0, 1 or 2
- c is 0, 1 or 2
- d is 0, 1 or 2
- a+b is 0 to 3
- c+d is 0 to 3 and
- a+b+c+d is 0 to 4 and
- wherein the organic phosphite is described by the formulae ##STR6## wherein R is an aliphatic, aromatic, alkyl substituted aromatic, aryl substituted aliphatic, cycloaliphatic, diphenyl or phenyl-alkylene-phenyl group having a valence equal to n, R' is an alkyl, hydroxyalkyl, aryl, aralkyl, alkaryl, alkenyl or cycloalkyl group, R" is a divalent or tetravalent aliphatic, aromatic or cycloaliphatic radical, R'" is an alkylene group optionally containing ether linkages, m is 1 or 2, n is an integer from 2 to 6 and p is an integer from 1 to 1000 and the organic phosphonite is described by the formulae ##STR7## wherein R.sup.5 is hydrogen, or an aliphatic, aromatic, alkyl substituted aromatic, aryl substituted aliphatic or cycloaliphatic radical having a valence of q, R.sup.6 is an alkyl, aryl, aralkyl, alkaryl, cycloalkyl or alkenyl group or the R.sup.6 groups together with the oxygen atoms and the phosphorus atom may join to form a heterocyclic ring, R.sup.7 is an alkyl, aryl, aralkyl, alkaryl, cycloalkyl or alkenyl group, R.sup.8 is an alkylene group optionally containing ether linkages, q is an integer from 1 to 6 and x is an integer from 1 to 1000.
A method of stabilizing substituted and unsubstituted 2-hydroxybenzophenones against color change comprising the step of adding to a color unstable substituted or unsubstituted 2-hydroxybenzophenone a color stabilizing amount of a phosphorus containing compound selected from the group consisting of organic phosphite and organic phosphonite wherein the substituted and unsubstituted 2-hydroxybenzophenone is given by the following formula. ##STR8## wherein R.sup.1 and R.sup.4 are the same or different and are selected from the group consisting of (1) hydrogen and (2) substituted and unsubstituted alkyl, aryl, alkaryl, aralkyl, alkenyl or cycloalkyl group wherein the substitutent is halogen,
- R.sup.2 and R.sup.3 are the same or different and are selected from the group consisting of R.sup.1, Br, Cl and alkoxy,
- a is 0, 1 or 2,
- b is 0, 1 or 2,
- c is 0, 1 or 2,
- d is 0, 1 or 2,
- a+b is 0 to 3
- c+d is 0 to 3 and
- a+b+c+d is 0 to 4 and
- wherein the organic phosphite is described by the formulae ##STR9## wherein R is an aliphatic, aromatic, alkyl substituted aromatic, aryl substituted aliphatic, cycloaliphatic, diphenyl or phenyl-alkylene-phenyl group having a valence equal to n, R' is an alkyl, hydroxyalkyl, aryl, aralkyl, alkaryl, alkenyl or cycloalkyl, R" is a divalent or tetravalent aliphatic, aromatic or cycloaliphatic radical, R'" is an alkylene group optionally containing ether linkages, m is 1 or 2, n is an integer from 2 to 6 and p is an integer from 1 to 1000 and the organic phosphonite is described by the formulae ##STR10## wherein R.sup.5 is hydrogen, or an aliphatic, aromatic, alkyl substituted aromatic, aryl substituted aliphatic or cycloaliphatic radical having a valence of q, R.sup.6 is an alkyl, aryl, aralkyl, alkaryl, cycloalkyl or alkenyl group or the R.sup.6 groups together with the oxygen atoms and the phosphorus atom may join to form a heterocyclic ring, R.sup.7 is an alkyl, aryl, aralkyl, alkaryl, cycloalkyl or alkenyl group, R.sup.8 is an alkylene group optionally containing ether linkages, q is an integer from 1 to 6 and x is an integer from 1 to 1000.
Dependencies are inferred from the claim text.