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US 4,304,944 AGranted
Bicyclic ketones
AssigneeFritzsche Dodge & Olcott Inc.
InventorsBrian J. Willis, Robert G. Eilerman
Life of this patent
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Abstract
Novel bicyclic ketones having the structure: ##STR1## wherein R is a C.sub.1 -C.sub.5 alkyl group, either straight-chain or branched, and saturated analogs have been prepared. These compounds exhibit floral and woody odors and/or desirable flavor properties, and are useful as fragrance and/or flavor materials. The compounds are conveniently prepared from alkylidene cyclopentanones by Michael addition with alkyl metalloacetoacetates and subsequent decarboxylative cyclization of the adducts. The saturated analogs may then be prepared by hydrogenation.
Claims5
A compound having the structure:
- ##STR12## wherein R is C.sub.1 -C.sub.5 alkyl and wherein the dashed line may be a carbon-carbon single bond or a carbon-carbon double bond.
Dependencies are inferred from the claim text.