Olefin polymerization catalyst
AssigneeSumitomo Chemical Company, Limited
InventorsAkinobu Shiga, Yoshiharu Fukui, Kazuhiro Matsumura, Toshio Sasaki, Masahisa Okawa
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AssigneeSumitomo Chemical Company, Limited
InventorsAkinobu Shiga, Yoshiharu Fukui, Kazuhiro Matsumura, Toshio Sasaki, Masahisa Okawa
Estimating the term…
A process for producing a solid titanium trichloride catalyst which comprises at a temperature of -40.degree. C. to 40.degree. C. mixing titanium tetrachloride with an organo-aluminum compound of the formula (I): AlR.sub.n X.sub.3-n (I) wherein R has up to 10 carbon atoms and is an aliphatic hydrocarbon group which may be straight chain, branched chain or cyclic, or an aromatic hydrocarbon group; X is a halogen atom or a hydrogen atom; and n is a number satisfying the relation, 1.5.ltoreq.n.ltoreq.3; in the presence of an ether compound of the formula (II): R.sup.2 OR.sup.3 (II) wherein R.sup.2 and R.sup.3, which may be the same or different, each is an alkyl group, an aralkyl group or an alkenyl group, each having up to 10 carbon atoms, to reduce the titanium tetrachloride; maintaining the mixed solution at a temperature of 10.degree. C. to 50.degree. C. thereby performing the reduction; at the time when the reduction reaction proceeds at least 90%, adding iodine to the resulting liquid titanium trichloride product; maintaining the resulting mixture at a temperature of about 30.degree. C. to about 150.degree. C. after the addition thereby precipitating solid titanium trichloride; and then separating the solid titanium trichloride.
A process for producing an olefin polymer comprising polymerizing an olefin with a catalyst system comprising
Dependencies are inferred from the claim text.