Conversion of synthesis gas to hydrocarbon mixtures utilizing a dual catalyst bed
AssigneeMobil Oil Corporation
InventorsJames A. Brennan, Philip D. Caesar, Julius Ciric, William E. Garwood
Life of this patent
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Abstract
A gaseous mixture of carbon monoxide and hydrogen is passed in contact over a first catalyst bed comprising an iron or cobalt containing Fischer-Tropsch catalyst in combination with a crystalline aluminosilicate of the class of crystalline zeolite represented by ZSM-5 so as to obtain a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90% overhead and being a predominantly olefinic product. The total products from said contact including said liquid hydrocarbon product are then converted over a second catalyst bed containing HZSM-5 to obtain a highly aromatic product, i.e., greater than 20 weight percent.
Claims10
In a process for converting synthesis gas comprising carbon monoxide and hydrogen to gasoline boiling components wherein synthesis gas is contracted in a first stage under conditions of elevated temperatures and pressure with a Fischer-Tropsch catalyst and the total product from said first stage contact is passed to a second stage containing an acidic crystalline zeolite having a pore diameter greater than about five Angstroms, a silica-to-alumina ratio of at least 12, a crystal density substantially below 1.6 grams per cubic centimeter and a constraint index of from 1 to 12 the improvement which comprises:
- (a) carrying out said contact in said first stage at a temperature of 450.degree.-750.degree. F., a space velocity of 500-20,000 GHSV, and a pressure of from 50 to 1000 psig, with a catalyst composite comprising an intimate mixture of an iron or cobalt-containing Fischer-Tropsch component and a volume excess of a crystalline aluminosilicate zeolite having a pore size greater than 5 Angstroms, a silica-to-alumina ratio of at least 12 and a constraint index of from about 1 to 12, wherein
- the activity of said crystalline aluminosilicate zeolite in said first stage is balanced with said Fischer-Tropsch component so as to obtain products including a liquid olefinic naphtha having a boiling range of less than 400.degree. F. at 90 percent overhead with an aromatic content of less than about 20 weight percent, an olefin plus aromatic content of at least 50 weight percent, wherein the olefins have predominantly branched chain double bonds;
- (b) operating said second stage at a temperature of from 550.degree. F. to about 800.degree. F., a pressure of from 50 to about 1000 psig and at a gas hourly space velocity of from 500 to 20,000;
- (c) recovering a C.sub.5 + gasoline fraction in a yield of at least 40 weight percent based on the total hydrocarbons produced, said gasoline fraction having a boiling range of less than 400.degree. F. at a 90 percent overhead and an aromatics content greater than 20 weight percent;
- and
- (d) producing methane plus ethane in an amount no greater than 30 weight percent.
In a process for converting synthesis gas comprising carbon monoxide and hydrogen to gasoline boiling components wherein synthesis gas is contacted in a first stage under conditions of elevated temperatures and pressure with a Fischer-Tropsch catalyst and the total product from said first stage contact is passed to a second stage containing an acidic crystalline zeolite having a pore diameter greater than about five Angstroms, a silica-to-alumina ratio of at least 12, a crystal density substantially below 1.6 grams per cubic centimeter and a constraint index of from 1 to 12 the improvement which comprises:
- (a) carrying out said contact in said first stage at a temperature of from 450.degree.-750.degree. F., a space velocity of 500-20,000 GHSV and a pressure from 50-1,000 psig with a catalyst composite comprising an intimate mixture of a potassium promoted iron Fischer-Tropsch component and a volume excess of a crystalline aluminosilicate zeolite having a pore size greater than five Angstroms, a silica-to-alumina ratio of at least 12 and a constraint index of from about 1 to 12, wherein
- the activity of said crystalline aluminosilicate zeolite in said first stage is balanced with said Fischer-Tropsch component so as to obtain products including a liquid olefinic naphtha having a boiling range of less than 400.degree. F. at 90% overhead with an aromatic content of less than about 20 weight percent, an olefin plus aromatic content of at least 50 weight percent, wherein the olefins have predominantly branched chain double bonds;
- (b) operating said second stage at a temperature of from 550.degree. F. to about 800.degree. F. a pressure of from 50 to about 1000 psig and at a gas hourly space velocity of from 500 to 20,000;
- (c) recovering a C.sub.5 + gasoline fraction in a yield of at least 40 weight percent based on the total hydrocarbons produced, said gasoline fraction having a boiling range of less than 400.degree. F. at a 90% overhead and an aromatic content greater than 20 weight percent;
- and
- (d) producing methane plus ethane in an amount no greater than 30 weight percent.
Dependencies are inferred from the claim text.