Novel trialkyl aluminum cocatalyst
AssigneeExxon Research & Engineering Co.
InventorArthur W. Langer
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Abstract
A new improved catalyst system for alpha-olefin type polymerizations, includes at least one metal alkyl compound having the formula R'"M in combination with a Group IVB-VIII transition metal compound on a support and at least one hindered Lewis base and one unhindered Lewis base and a Group IA-IIIA metal salt of a sterically hindered carboxylate, alkoxide or aryloxide, wherein R'" is selected from the group consisting of C.sub.1 to C.sub.20 primary alkyl, alkenyl or aralkyl groups, or a hydride, and M is selected from the group consisting of aluminum, gallium, or indium. The improved catalyst system provides polymers having increased isotactic stereoregularity as well as lower catalyst residue.
Claims18
A catalyst composition which comprises a mixture of:
- (a) at least one alkyl metal compound having the formula R.sub.3 '''M, wherein M=Al, Ga, or In, R''' is selected from the group consisting of C.sub.1 to C.sub.20 primary, branched primary, secondary, or tertiary alkyl, cycloalkyl, alkenyl and aralkyl groups and hydride and mixtures thereof;
- (b) a Group IVB-VIII transition metal compound on a layer lattice support, a molar ratio of said R.sub.3 '''M to said transition metal compound being about 0.5:1 to 200:1;
- (c) at least one hindered Lewis base, said Lewis base not causing excessive cleavage of metal-carbon bonds or loss of active sites, under polymerization conditions hindered Lewis bases being those whose complexing ability toward the cocatalyst is hindered sufficiently by steric and/or electronic effects to cause appreciable dissociation of the trialkyl metal Lewis base complex under polymerization conditions;
- (d) A Group IA to Group IIIA metal salt selected from the group consisting of sterically hindered carboxylates, alkoxides and aryloxides;
- and
- (e) at least one unhindered Lewis base, said unhindered base not causing excessive cleavage of metal-carbon bonds or loss of active sites under polymerization conditions.
Dependencies are inferred from the claim text.