Process for releasing ammonia bound in coal water
AssigneeFirma Carl Still GmbH & Co. KG
InventorsHeinrich Weber, Dieter Laufhutte
Life of this patent
Estimating the term…
Loading patent…
AssigneeFirma Carl Still GmbH & Co. KG
InventorsHeinrich Weber, Dieter Laufhutte
Estimating the term…
A process for releasing ammonia which is bound in coal water using a pre-desulfurization plant having ammonia and hydrogen sulfide scrubbers through which crude coking plant gas is passed comprises circulating the crude coke oven gases through the hydrogen sulfide scrubber and the ammonia scrubber in succession, directing the coal water first through the ammonia scrubber while the crude coking plant gases are being also circulated therethrough after passing it first through the hydrogen sulfide scrubber. An alkali solution is also circulated through the ammonia scrubber to enrich the solution with acid components and to liberate ammonia bound in the coal water directing the coal water which has been enriched from the ammonia scrubber into the hydrogen sulfide scrubber. The process is characterized by the fact that the alkali solution which has first served for the hydrogen sulfide scrubber is added to the ammonia hydrogen sulfide scrubber. 80 to 90% of the total alkali solution is charged to the hydrogen sulfide after-washery and then on the hydrogen sulfide pre-washery and the rest is charged to an ammonia expulsion apparatus.
A process for releasing ammonia bound in coal water containing the ammonia in the form of salts of strong acids in an ammonia-hydrogen sulfide scrubbing process of a combined pre-desulfurization and ammonia removal plant having a hydrogen scrubber and an ammonia scrubber, the scrubbing process being of the type wherein raw coke oven gas containing ammonia and hydrogen sulfide is passed into the hydrogen scrubber, scrubbed with ammonical water received in the hydrogen scrubber from the ammonia scrubber to form a prepurified gas, and in which the prepurified gas is then passed into the ammonia scrubber and scrubbed with water to form the ammonical water to be used in the hydrogen scrubber, the improvement wherein the water passed in the ammonia scrubber is the coal water, and further comprising the steps of then passing the coal water into the hydrogen sulfide scrubber, scrubbing the prepurified gas in the ammonia scrubber with an aqueous alkali solution after the prepurified gas is scrubbed with the coal water to form an alkali solution enriched with acid components, and passing the enriched alkali solution into the hydrogen sulfide scrubber to liberate the ammonia bound in the coal water.
Dependencies are inferred from the claim text.