Light ends recovery in ethyl acrylate process
AssigneeCelanese Corporation
InventorsTheodore Horlenko, James L. Paul, James W. Gordon
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Abstract
A normally liquid hydrocarbon having a minimum boiling point of about 425.degree. F. is utilized to provide the liquid seal in a vacuum pump which intakes a gaseous light ends stream resulting from a process for the production of ethyl acrylate by the reaction of ethylene with acrylic acid in the presence of a sulfuric acid catalyst. Upon contact in the vacuum pump, the gaseous light ends are partially absorbed into the normally liquid hydrocarbon, with the normally liquid hydrocarbon being recovered by fractionation.
Claims13
In a process for the production of ethyl acrylate by the reaction of ethylene with acrylic acid in the presence of a sulfuric acid catalyst wherein the reaction products are distilled in a vacuum distillation system at a reduced pressure less than atmospheric to obtain a liquid ethyl acrylate product and also resulting in a first gaseous light ends stream from said vacuum distillation system containing sulfur dioxide and also containing ethylene, ethyl acrylate and other organic light ends by-products, which said first gaseous light ends stream passes through a vacuum pump providing the reduced pressure for said vacuum distillation system, which said vacuum pump utilizes a liquid seal fluid to provide a liquid seal therein and in which said vacuum pump said first gaseous light ends stream mixes with and is partially absorbed in said liquid seal fluid to result in a gas-liquid mixture which is discharged from said vacuum pump, and which said gas-liquid mixture so discharged is fractionated to recover a liquid recycle stream comprising liquid seal fluid and which said liquid recycle stream is recycled to said vacuum pump, the improvements which comprise (a) utilizing as said liquid seal fluid a normally liquid hydrocarbon which has a minimum boiling point of 425.degree. F. and 90% by weight of which boils within the range of about 425.degree. F. to 800.degree. F., and (b) fractionating said gas-liquid mixture so discharged as to recover a said liquid recycle stream comprising said liquid seal fluid which is substantially free of sulfur dioxide and does not contain in excess of about 40% by weight of ethyl acrylate.
Dependencies are inferred from the claim text.