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US 4,300,996 AGranted
Three-stage coal liquefaction process
AssigneeChevron Research Company
InventorChristopher W. Kuehler
Life of this patent
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Abstract
Disclosed is a three-stage process for liquefying coal in which a coal-solvent slurry is sequentially passed through a first dissolving stage and two catalytic reaction stages in series. The first catalytic reaction stage contains a catalyst having a selectivity for converting heptane insolubles to lower molecular weight compounds and a portion of the effluent from said stage is recycled for use as solvent in the dissolver. The second catalytic reactor is operated under hydrocracking conditions.
Claims4
A three-stage process for liquefying coal which comprises:
- forming a coal-solvent slurry by mixing subdivided coal with a solvent;
- passing said slurry through a dissolving stage free of external catalyst and contact particles at a temperature in the range of 400.degree.-480.degree. C. and at a slurry hourly space velocity in the range of 1-150 hr..sup.-1 to substantially dissolve said coal and produce an effluent comprising dissolved coal, solvent, insoluble solids and heptane insolubles;
- passing effluent containing the dissolved coal and the insoluble solids from said dissolving stage with added hydrogen through a first catalytic reaction stage containing a catalyst having a selectivity for converting heptane insolubles to lower molecular weight compounds, at a temperature in the range of 340.degree.-430.degree. C., a slurry hourly space velocity in the range of 0.5 to 5 hr..sup.-1, and a hydrogen partial pressure in the range of 35 to 700 atmospheres;
- recycling a portion of the effluent from said first catalytic reaction stage for use as solvent;
- and
- passing the remainder of said effluent from said first catalytic reaction stage through a second catalytic reaction stage containing hydrocracking catalyst and operating under hydrocracking conditions including a hydrogen partial pressure in the range of 35-700 atmospheres and at a temperature in the range of 340.degree.-430.degree. C.
3 more elements
Dependencies are inferred from the claim text.