Process for deterrent coating of triple base propellant compositions

A process for preparation of progressive burning propellant granules from strands of propellant prior to drying of said strands to remove processing solvents, the propellant composition of said strands comprising nitrocellulose, energetic nitrate ester plasticizer and nitroguanidine, said process comprising:

• (a) contacting the exterior surface of the solvent-wet propellant strand with a nonaqueous mixture comprising a burning rate deterrent and a solvent, said burning rate deterrent being selected from dimethyl diphenyl urea, diethyl diphenyl urea, ethylene dimethacrylate, lead-2-ethyl hexoate and linear polyesters capable of diffusing into said propellant strand, said polyesters having a weight average molecular weight of from about 1,500 to about 30,000, a melting point not exceeding 190.degree. F. and being substantially nonmigrating within said propellant strand at temperatures below 150.degree. F., and continuing contact for a time sufficient to permit the burning rate deterrent to penetrate the surface of said strand,
• (b) promptly washing excess mixture of burning rate deterrent and solvent from the surface of said strand with water and cutting said strand of deterrent coated propellant into granules, the order of the steps of washing and cutting being interchangeable provided washing is conducted promptly, and
• (c) drying the resulting deterrent coated granules.