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US 4,298,720 AGranted
Thermosetting resin composition from maleimide compound and alkenyl phenol
AssigneeMitsui Toatsu Chemicals, Inc.
InventorsNoboru Yamazaki, Tsutomu Takase, Yoshio Morimoto, Teruo Yuasa
Life of this patent
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Abstract
Disclosed is a heat-resistant and fast-curing thermosetting resin composition suitably for insulating materials and comprising (a) a bismaleimide and/or a polymaleimide compound and (b) at least one compound selected from alkenylphenol derivatives, linear dimers thereof, and polymers thereof. In addition to components (a) and (b), this resin composition can contain (c) a polymerizable unsaturated compound.
Claims7
A thermosetting resin composition comprising:
- (a) at least one maleimide compound selected from the group consisting (i) bismaleimides having the formula ##STR17## where R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are the same or different from each other and are:
- hydrogen atoms;
- or halogen atoms;
- or straight-chain or branched alkyl radicals of from 1 to 10 carbon atoms;
- or phenyl radicals;
- or substituted phenyl radicals having one or more substituents selected from the straight-chain or branched alkyl radicals of from 1 to 10 carbon atoms, halogen atoms, R.sub.13 O--groups in which R.sub.13 is an aliphatic radical of from 1 to 5 carbon atoms, and, when there are two or more radicals represented by R.sub.13, said radicals are identical to or different from each other, ##STR18## groups in which R.sub.13 is as previously defined, hydroxyl groups, or cyano groups;
- and Z is a divalent organic radical of at least 2 carbon atoms;
- and
- (ii) polymaleimides having the formula ##STR19## where R.sub.5, R.sub.6, R.sub.7, R.sub.8, R.sub.9, and R.sub.10 are the same or different from each other and are hydrogen atoms;
- or halogen atoms;
- or straight-chain or branched alkyl radicals of from 1 to 10 carbon atoms;
- or phenyl radicals;
- or substituted phenyl radicals having one or more substituents selected from halogen atoms, straight-chain or branched alkyl radical of from 1 to 10 carbon atoms, R.sub.13 O--groups in which R.sub.13 is as previously defined, ##STR20## groups in which R.sub.13 is as previously defined, hydroxyl group, or cyano groups;
- and n is zero or a positive number;
- and
- (b) at least one alkenylphenol derivative selected from the groups consisting of compounds having the formula ##STR21## where R.sub.11 is a hydrogen atom;
- or halogen atom;
- or straight-chain or branched alkyl radical of from 1 to 10 carbon atoms;
- or phenyl radical;
- or substituted phenyl radical having one or more substituents selected from halogen atoms, straight-chain or branched alkyl radicals of from 1 to 10 carbon atoms, R.sub.13 O--groups in which R.sub.13 is as previously defined, ##STR22## groups in which R.sub.13 is as previously defined, hydroxyl groups, or cyano groups;
- X is a hydrogen atom;
- or a halogen atom;
- or a carboxyl group;
- or an ##STR23## group in which R.sub.13 is as previously defined;
- or a R.sub.13 O--group in which R.sub.13 is as previously defined;
- or a cyano group;
- Y is a hydroxyl group;
- or a R.sub.13 O--group in which R.sub.13 is as previously defined;
- or a glycidyloxy group;
- or an aryloxy group;
- or a substituted aryloxy group having one or more substituents selected from halogen atoms or straight-chain or branched alkyl radicals of from 1 to 5 carbon atoms;
- or a propargyloxy group;
- or a substituted propargyloxy group having one or more substituents selected from halogen atoms or straight-chain or branched alkyl radicals of from 1 to 5 carbon atoms;
- or an ##STR24## group in which R.sub.14 is an aliphatic radical of from 1 to 20 carbon atoms;
- or an aromatic radical;
- and m.sub.1 and m.sub.2 are positive integers and the sum of m.sub.1 +m.sub.2 has the value of 5.
33 more elements
Dependencies are inferred from the claim text.