Combined process for the production of urea and ammonia
AssigneeSnamprogetti S.p.A.
InventorsGiorgio Pagani, Vincenzo Lagana, Francesco Saviano
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Abstract
In an integrated or combined process for the production of ammonia and urea, the improvement consisting in that the absorption of CO.sub.2 from the raw gas going to the synthesis reactor for ammonia is carried out with an absorption apparatus which is divided into two sections, one being of the plate type and the other of the thin film type. The predominant fraction of CO.sub.2 is stripped in the thin-film section, the remainder in the adiabatic plate section.
Claims7
In a method for the concurrent production of ammonia and urea comprising the steps of producing ammonia in an ammonia-synthesis apparatus, absorbing ammonia at the exit of the ammonia-synthesis reactor with water, thus obtaining a concentrated aqueous solution of ammonia, utilizing the concentrated solution of ammonia for the absorption of the CO.sub.2 contained in the raw gases for the synthesis of ammonia, obtaining ammonium carbamate, converting the ammonium carbamate partially into urea in a urea-synthesis reactor, thermally decomposing the carbamate which has not been converted into urea and stripping the decomposition products with a gas selected from the group consisting of ammonia, CO.sub.2 and inerts, discharging from the stripping zone a solution of urea which still contains carbamate, recycling the products of decomposition of the carbamate to the urea-synthesis reactor, distilling under a pressure of from 3 to 30 atm, in at least one stage, the solution of urea to obtain liquid ammonia and one or more ammoniacal solutions of ammonium carbonate, and an aqueous solution of urea deprived of ammonium carbamate the improvement which comprises introducing the CO.sub.2 -containing gas at the bottom, or near the bottom, of an absorber which is split into two sections, the lower section being a film-absorber and the upper section being a plate-absorber, the absorbing solution in the upper section being the concentrated aqueous solution of ammonia aforesaid, the absorbing solution in the lower section being one or more of the aqueous ammoniacal solutions of ammonium carbonate as obtained by distillation of the solution of urea under a pressure of from 3 to 30 atm. with addition of liquid ammonia.
Dependencies are inferred from the claim text.