A purification process for residual industrial gases having a water content of from about 24 to about 34% and containing small quantities of H.sub.2 S, SO.sub.2, CS.sub.2, COS or sulfur vapor, as well as large quantities of CO.sub.2 and N.sub.2, comprising subjecting the residual gases to a catalytic reduction to transform the sulfur containing compounds in said residual gases into H.sub.2 S, washing the residual gases with an aqueous amine solution to form a H.sub.2 S enriched aqueous amine solution and effluent gases and discharging the burnt effluent gases to the atmosphere, regenerating the H.sub.2 S enriched aqueous amine solution by heating to produce gases comprising H.sub.2 S and CO.sub.2 and regenerated aqueous amine solution, and, returning said gases comprising H.sub.2 S and CO.sub.2 to a sulfur manufacturing unit;
- characterized in that the temperature of the gases in the process are permanently maintained at a level higher than the dew point of the water contained in the gases at each point in the process such that the H.sub.2 O contained in the residual gases is discharged into the atmosphere with said burnt effluent gases.