Preparation of polyisocyanates from polycarbamates

Abstract

In the process of producing polyisocyanates by (a) condensing an alkyl-N-phenylcarbamate having 1 to 3 carbons in the alkyl moiety in the presence of an acid to produce condensate containing diphenylmethane dicarbamates and polymethylene polyphenyl carbamates with by-product N-benzyl compounds, rearranging said N-benzyl compounds in said condensate with acid catalyst to obtain a pyrolysis feed mixture containing diphenylmethane dicarbamates, polymethylene polyphenyl carbamates and 0.02 to 1.0 percent by weight of amine impurities as NH.sub.2 groups, and (b) thermally decomposing the carbamate moieties in the pyrolysis feed mixture to isocyanate moieties to produce polyisocyanates, the improvement comprises increasing the percent isocyanate content of said polyisocyanates by prior to step (b) converting any amine salt by-products in said pyrolysis feed mixture to free amine by-products by contacting the mixture with a weakly basic tertiary amine anion exchange resin and removing any free amine by-products by contacting the feed mixture with a strongly acidic sulfonated polyaromatic ion exchange resin whereby the amine impurity in the pyrolysis feed mixture is reduced to less than 0.001 percent by weight as NH.sub.2 groups.

Dependencies are inferred from the claim text.