Regeneration of ferric ions in coal desulfurization process
AssigneePhillips Petroleum Company
InventorEdward L. Czenkusch
Life of this patent
Estimating the term…
Abstract
A process for removing sulfur from coal using a ferric solution wherein iron loss by precipitation of insoluble iron compounds is controlled by regulation of the hydrogen ion concentration of the reaction slurry. The pH or other measurable condition at which the process is at least self-sustaining with respect to ferric ions is determined for a particular coal sample. The reaction slurry is monitored for changes in the chosen condition which signal a loss of iron from solution, and acid is automatically added as needed to prevent iron precipitation or to return precipitated iron to solution.
Claims23
A process for treating coal which comprises:
- contacting the coal with an aqueous desulfurization reagent containing ferric ions and producing a reaction slurry comprising ferric ions, ferrous ions and hydrogen ions;
- maintaining the hydrogen ion concentration of the reaction slurry at a level which inhibits precipitation of iron solids.
A process for treating coal which comprises:
- contacting coal containing at least one naturally-occurring base with an aqueous desulfurization reagent containing ferric ions and producing a reaction slurry comprising ferric ions, ferrous ions and hydrogen ions;
- regenerating ferric ions by oxidation of the ferrous ions;
- maintaining the hydrogen ion concentration of the reaction slurry at a level which inhibits precipitation of iron solids during the regenerating step.
Dependencies are inferred from the claim text.