Ethylene polymerization process
AssigneeGulf Oil Corporation
InventorsRobert W. Hill, William L. Kehl, Thomas J. Lynch
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AssigneeGulf Oil Corporation
InventorsRobert W. Hill, William L. Kehl, Thomas J. Lynch
Estimating the term…
Novel catalysts are provided for the polymerization of olefins such as ethylene. The catalysts consist essentially of a chromium compound supported upon an inorganic carrier containing aluminum and phosphorus moieties, at least a portion of the chromium having a valence of less than 6. The inorganic carrier is an amorphous precipitate of aluminum phosphate or an amorphous precipitate containing aluminum and phosphorus moieties in an atomic ratio in the range of about 5:1 to 1:1. The catalysts are particularly useful for polymerizing ethylene in a Particle Form Process in that the catalyst has essentially no polymerization induction period and provides ethylene polymers having a desirably broad molecular weight distribution and a desirably high melt flow shear ratio.
In a Particle Form Process for the polymerization of ethylene, the improvement which comprises employing as the polymerization catalyst a catalyst prepared by depositing a chromium compound upon an amorphous inorganic carrier containing aluminum and phosphorus moieties;
In a Particle Form Process for the polymerization of ethylene, the improvement which comprises employing as the polymerization catalyst a catalyst prepared by depositing a chromium compound upon an amorphous inorganic carrier containing aluminum and phosphorus moieties;
In a Particle Form Process for the polymerization of ethylene, the improvement which comprises employing as the polymerization catalyst a catalyst prepared by
Dependencies are inferred from the claim text.