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US 4,289,653 AGranted
Comulled silica-alumina base denitrification catalyst
AssigneeChevron Research Company
InventorJoseph Jaffe
Life of this patent
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Abstract
An extruded silica-alumina base catalyst is prepared by cogelling a silica sol solution containing aluminum and having a pH in the range of about 1-3. The cogelled silica-alumina is peptized to form an extrudable dough and may be mulled with Group VI-B and Group VIII metals to prepare a denitrification catalyst extrudable composition.
Claims4
An extruded silica-alumina catalyst prepared by the method which consists essentially of the following steps:
- mixing a sodium silicate solution with an aqueous aluminum sulfate solution and sulfuric acid to form an acidified silica sol in an alumina salt solution having a pH in the range of about 1 to 3;
- adding sufficient ammonium hydroxide to said acidified silica sol in the aluminum salt solution to form a cogelled mass of silica and alumina under substantially constant pH conditions and at a pH of at least 4;
- adding additional ammonium hydroxide to the cogelled mass to obtain a pH in the range of 7.5 to 8.5;
- washing the cogelled mass;
- mulling the cogelled mass with a peptizing agent, a Group VI-B metal compound and a Group VIII metal compound to form an extrudable dough;
- extruding said dough;
- and drying and calcining the extruded dough.
4 more elements
Dependencies are inferred from the claim text.