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US 4,288,519 AGranted
Dual purpose electrophotographic magnetic toner and process of making
AssigneeBlack Copy Company, Inc.
InventorsArthur S. Diamond, Sydney N. Floersheim
Life of this patent
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Abstract
A free-flowing, non-spherical, fragmentary, toner particle is prepared by blending a mixture of thermoplastic resins with magnetic iron oxide. The dispersion is processed to a fine powder and dry blended with conductive carbon black which is anchored onto the surface of the particle by warm air or gas.
Claims9
A method of producing a dual purpose, single component, electronically conductive, magnetically attractable toner comprising the steps of:
- heating and mixing a mixture of thermoplastic toner resins to form an intimate blend while dispersing therein 50 to 150 phr of finely divided, magnetic pigment and 0 to 15 phr of conductive pigment, said resins consisting essentially of a linear polyester consisting of the condensation product of an aromatic diol with an unsaturated aliphatic, dibasic acid having a softening point from 95.degree. C. to 115.degree. C. and an ethylene-vinyl acetate copolymer containing 5 to 40% vinyl acetate and the ratio of polyester to copolymer being from 1:1 to 5:1;
- cooling the mixture to a brittle solid;
- breaking the mixture into large fragments;
- grinding the fragments to form coarse particles;
- fine grinding the coarse particles to form fine, fragmentary aspherical, acicular particles having a diameter from 10 to 40 microns by subjecting the particles to jets of inert gas in absence of abrasive such that they fragment by self-impact;
- dry blending the fine particles with from 0.5 to 2.0 percent by weight of finely divided conductive pigment having a particle diameter in the range of 10-80 milimicrons;
- and
- embedding the conductive pigment on the surface of the fine, acicular, aspherical particles without changing the shape thereof by gravity feeding the dry blend into the top of a spray drier and heating the falling particles in a 250.degree.-350.degree. F. gas stream to a temperature just sufficient to soften the thermoplastic resin.
5 more elements
Dependencies are inferred from the claim text.