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US 4,288,391 AGranted
Alkylated 2,2'-biphenylene phosphites
AssigneeCiba-Geigy Corporation
InventorJohn D. Spivack
Life of this patent
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Abstract
Alkylated 1,1'-biphenyl-2,2'diyl phosphites are prepared by reacting alkylated 2,2'-biphenol with phosphorous trichloride in an organic solvent and then reacting the intermediate with an alcohol or thiol. Said phosphites are useful as stabilizers of organic polymers and lubricating oils, especially as process stabilizers for polyolefins, elastomers, polyesters and polycarbonates.
Claims8
A 1,1'-biphenyl-2,2'-diyl phosphite of the formula ##STR9## wherein R is an alkyl group of 1 to 18 carbon atoms,
- R.sup.1 is hydrogen or alkyl group of 1 to 18 carbon atoms, and
- R.sup.2 is an alkyl group of 1 to 20 carbon atoms, phenyl, phenyl substituted by 1 to 3 alkyl groups each having 1 to 8 carbon atoms, or by two alkyl groups each having 1 to 8 carbon atoms and by --COOR.sup.4 where R.sup.4 is alkyl of 1 to 18 carbon atoms,
- R.sup.3 is an n-valent radical selected from the group consisting of a straight- or branched-chain alkylene of 2 to 12 atoms, a straight- or branched chain alkane-triyl, -tetrayl, -pentayl or -hexayl of 3 to 6 carbon atoms, alkylene of 4 to 6 carbon atoms, cycloalkylene of 6 to 12 carbon atoms, 1,4-cyclohexanedimethylene, arylene or arylene or arenetriyl of 6 to 10 carbon atoms, p-xylylene, phenylene-E-phenylene where E is a direct bond, --O--, --S--, --NR.sup.5 --, where R.sup.5 is alkyl of 1 to 18 carbon atoms;
- a straight- or branched chain alkylene or alkylidene of 1 to 12 carbon atoms or cycloalkylidene of 5 to 6 carbon atoms, said arylene or said phenylene-E-phenylene substituted by 1 to 4 alkyl groups each having 1 to 8 carbon atoms, --(CH.sub.2).sub.x X(CH.sub.2).sub.x where x is 2 to 6, dipentaerythrityl, and ##STR10## where Y is hydrogen, methyl or ethyl and z is 1 to 10,
- X is oxygen or sulfur, and n is 2 to 6.
2 more elements
Dependencies are inferred from the claim text.